Charge transfer drives anomalous phase transition in ceria
Nanosized ceria has conventionally been thought to have a cubic fluorite structure. Here, the authors use a combination of experiments and simulations to show that oxygen vacancies in ceria promote a charge-transfer induced phase transition from tetragonal to cubic.
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Autores principales: | He Zhu, Chao Yang, Qiang Li, Yang Ren, Joerg C. Neuefeind, Lin Gu, Huibiao Liu, Longlong Fan, Jun Chen, Jinxia Deng, Na Wang, Jiawang Hong, Xianran Xing |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
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Materias: | |
Acceso en línea: | https://doaj.org/article/adcd860d72c0421c8136473f6686fe3d |
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