Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts

Single-atom alloys are promising catalysts for a number of different reactions. Here, the authors demonstrate that carbon monoxide can be used to transition a PdAu catalyst between a single atom and a cluster phase which exhibit distinct selectivities for ethanol dehydrogenation.

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Autores principales:	Mengyao Ouyang, Konstantinos G. Papanikolaou, Alexey Boubnov, Adam S. Hoffman, Georgios Giannakakis, Simon R. Bare, Michail Stamatakis, Maria Flytzani-Stephanopoulos, E. Charles H. Sykes
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ae7b3a5240b4424cac0e0136eb05bd9c
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spelling	oai:doaj.org-article:ae7b3a5240b4424cac0e0136eb05bd9c2021-12-02T13:30:08ZDirecting reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts10.1038/s41467-021-21555-z2041-1723https://doaj.org/article/ae7b3a5240b4424cac0e0136eb05bd9c2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21555-zhttps://doaj.org/toc/2041-1723Single-atom alloys are promising catalysts for a number of different reactions. Here, the authors demonstrate that carbon monoxide can be used to transition a PdAu catalyst between a single atom and a cluster phase which exhibit distinct selectivities for ethanol dehydrogenation.Mengyao OuyangKonstantinos G. PapanikolaouAlexey BoubnovAdam S. HoffmanGeorgios GiannakakisSimon R. BareMichail StamatakisMaria Flytzani-StephanopoulosE. Charles H. SykesNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Mengyao Ouyang Konstantinos G. Papanikolaou Alexey Boubnov Adam S. Hoffman Georgios Giannakakis Simon R. Bare Michail Stamatakis Maria Flytzani-Stephanopoulos E. Charles H. Sykes Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
description	Single-atom alloys are promising catalysts for a number of different reactions. Here, the authors demonstrate that carbon monoxide can be used to transition a PdAu catalyst between a single atom and a cluster phase which exhibit distinct selectivities for ethanol dehydrogenation.
format	article
author	Mengyao Ouyang Konstantinos G. Papanikolaou Alexey Boubnov Adam S. Hoffman Georgios Giannakakis Simon R. Bare Michail Stamatakis Maria Flytzani-Stephanopoulos E. Charles H. Sykes
author_facet	Mengyao Ouyang Konstantinos G. Papanikolaou Alexey Boubnov Adam S. Hoffman Georgios Giannakakis Simon R. Bare Michail Stamatakis Maria Flytzani-Stephanopoulos E. Charles H. Sykes
author_sort	Mengyao Ouyang
title	Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
title_short	Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
title_full	Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
title_fullStr	Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
title_full_unstemmed	Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
title_sort	directing reaction pathways via in situ control of active site geometries in pdau single-atom alloy catalysts
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/ae7b3a5240b4424cac0e0136eb05bd9c
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Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts

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