Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures

The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g<sup>−1</sup>) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have...

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Autores principales:	Baoyou Liu, Xinyu Wang, Jie Tian, Peiwen Zhang, Huilong Yang, Nanxi Jin
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	ionic liquid 1-ethyl-3-methylimidazolium trifluoroacetate triethanolamine viscosity NO<sub>2</sub> absorption Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/ae7b78f586374769a9be41e6c16bd2c0
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spelling	oai:doaj.org-article:ae7b78f586374769a9be41e6c16bd2c02021-11-25T18:28:41ZExperimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures10.3390/molecules262269531420-3049https://doaj.org/article/ae7b78f586374769a9be41e6c16bd2c02021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6953https://doaj.org/toc/1420-3049The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g<sup>−1</sup>) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. The molar fraction of [EMIM] [TFA] dependence of the viscosity and absorption capacity was demonstrated. The addition of a small amount of [EMIM] [TFA] into TEA led to rapidly decreased rates of binary blends’ viscosity and absorption capacity. However, the viscosity and absorption of binary blends did not decrease significantly when [EMIM] [TFA] was increased to a specific value. Compared with the molar fraction of the solution, the temperature had no obvious effect on viscosity and absorption capacity. By modeling and optimizing the ratio of viscosity and absorption capacity of ([EMIM] [TFA] + TEA), it is proven that when the mole fraction of [EMIM] [TFA] is 0.58, ([EMIM] [TFA] + TEA) has the best viscosity and absorption capacity at the same time. In addition, at 303.15 K, ([EMIM] [TFA] + TEA) was absorbed and desorbed six times, the absorption slightly decreased, and the desorption increased.Baoyou LiuXinyu WangJie TianPeiwen ZhangHuilong YangNanxi JinMDPI AGarticleionic liquid1-ethyl-3-methylimidazolium trifluoroacetatetriethanolamineviscosityNO<sub>2</sub> absorptionOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6953, p 6953 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	ionic liquid 1-ethyl-3-methylimidazolium trifluoroacetate triethanolamine viscosity NO<sub>2</sub> absorption Organic chemistry QD241-441
spellingShingle	ionic liquid 1-ethyl-3-methylimidazolium trifluoroacetate triethanolamine viscosity NO<sub>2</sub> absorption Organic chemistry QD241-441 Baoyou Liu Xinyu Wang Jie Tian Peiwen Zhang Huilong Yang Nanxi Jin Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
description	The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g<sup>−1</sup>) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. The molar fraction of [EMIM] [TFA] dependence of the viscosity and absorption capacity was demonstrated. The addition of a small amount of [EMIM] [TFA] into TEA led to rapidly decreased rates of binary blends’ viscosity and absorption capacity. However, the viscosity and absorption of binary blends did not decrease significantly when [EMIM] [TFA] was increased to a specific value. Compared with the molar fraction of the solution, the temperature had no obvious effect on viscosity and absorption capacity. By modeling and optimizing the ratio of viscosity and absorption capacity of ([EMIM] [TFA] + TEA), it is proven that when the mole fraction of [EMIM] [TFA] is 0.58, ([EMIM] [TFA] + TEA) has the best viscosity and absorption capacity at the same time. In addition, at 303.15 K, ([EMIM] [TFA] + TEA) was absorbed and desorbed six times, the absorption slightly decreased, and the desorption increased.
format	article
author	Baoyou Liu Xinyu Wang Jie Tian Peiwen Zhang Huilong Yang Nanxi Jin
author_facet	Baoyou Liu Xinyu Wang Jie Tian Peiwen Zhang Huilong Yang Nanxi Jin
author_sort	Baoyou Liu
title	Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_short	Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_full	Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_fullStr	Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_full_unstemmed	Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
title_sort	experimental research on no<sub>2</sub> viscosity and absorption for (1-ethyl-3-methylimidazolium trifluoroacetate + triethanolamine) binary mixtures
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/ae7b78f586374769a9be41e6c16bd2c0
work_keys_str_mv	AT baoyouliu experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures AT xinyuwang experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures AT jietian experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures AT peiwenzhang experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures AT huilongyang experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures AT nanxijin experimentalresearchonnosub2subviscosityandabsorptionfor1ethyl3methylimidazoliumtrifluoroacetatetriethanolaminebinarymixtures
_version_	1718411097972670464

Experimental Research on NO<sub>2</sub> Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures

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