Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property

Abstract This study is focused on novel anti-corrosive support. This coating is based on the mixed matrix (MM) including epoxy and its hardener as thermoset polymer, melamine–formaldehyde as the organic phase, activated graphite as both inorganic and conductive phases, as well as wollastonite nanopa...

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Autores principales:	Rouholah Dordane, Mohammad Mahdi Doroodmand
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/aebe5d70bfcb45648364deaaf7debe22
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spelling	oai:doaj.org-article:aebe5d70bfcb45648364deaaf7debe222021-12-02T13:57:48ZNovel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property10.1038/s41598-021-81875-42045-2322https://doaj.org/article/aebe5d70bfcb45648364deaaf7debe222021-01-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-81875-4https://doaj.org/toc/2045-2322Abstract This study is focused on novel anti-corrosive support. This coating is based on the mixed matrix (MM) including epoxy and its hardener as thermoset polymer, melamine–formaldehyde as the organic phase, activated graphite as both inorganic and conductive phases, as well as wollastonite nanoparticles as filler. The wollastonite nanoparticles are synthesized by the new and novel method as suitable etching using hydrofluoric acid, “HF” at room temperature (25 ℃). The synthesized wollastonite nanoparticles are then adapted as a suitable filler during the formation of a new type of MM anti-corrosive coating for the preservation of metals form any corrosion. According to the results, during coating the MM, significant positive characteristics such as enough positive open circuit potential (OCP), small enough (i corr ), low cost, significant chemical/mechanical stability and acceptable flexibility are observed. Based on to the weight-loss analysis test on the MM-modified stainless steel during a 42-day time interval, the corrosion rate % is decreased from 74.86 to 0.34. In addition, the electrochemical impedance spectroscopy reveals major enhancements in the double-layer resistance and solution resistance of the cell system. Based on the electrochemical measurements, noticeable reduction and enhancement are observed in the correction rate and potential, respectively, during introducing hard corrosive conditions such as NaCl (3.0%, w/v) and HCl (1.0 mol L−1) environments that reveal the acceptable anti-corrosive behavior of the synthesized MM. The introduced MM is therefore considered as low cost, safe, eco-friendly, industrial-justified anti-corrosion support.Rouholah DordaneMohammad Mahdi DoroodmandNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Rouholah Dordane Mohammad Mahdi Doroodmand Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
description	Abstract This study is focused on novel anti-corrosive support. This coating is based on the mixed matrix (MM) including epoxy and its hardener as thermoset polymer, melamine–formaldehyde as the organic phase, activated graphite as both inorganic and conductive phases, as well as wollastonite nanoparticles as filler. The wollastonite nanoparticles are synthesized by the new and novel method as suitable etching using hydrofluoric acid, “HF” at room temperature (25 ℃). The synthesized wollastonite nanoparticles are then adapted as a suitable filler during the formation of a new type of MM anti-corrosive coating for the preservation of metals form any corrosion. According to the results, during coating the MM, significant positive characteristics such as enough positive open circuit potential (OCP), small enough (i corr ), low cost, significant chemical/mechanical stability and acceptable flexibility are observed. Based on to the weight-loss analysis test on the MM-modified stainless steel during a 42-day time interval, the corrosion rate % is decreased from 74.86 to 0.34. In addition, the electrochemical impedance spectroscopy reveals major enhancements in the double-layer resistance and solution resistance of the cell system. Based on the electrochemical measurements, noticeable reduction and enhancement are observed in the correction rate and potential, respectively, during introducing hard corrosive conditions such as NaCl (3.0%, w/v) and HCl (1.0 mol L−1) environments that reveal the acceptable anti-corrosive behavior of the synthesized MM. The introduced MM is therefore considered as low cost, safe, eco-friendly, industrial-justified anti-corrosion support.
format	article
author	Rouholah Dordane Mohammad Mahdi Doroodmand
author_facet	Rouholah Dordane Mohammad Mahdi Doroodmand
author_sort	Rouholah Dordane
title	Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
title_short	Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
title_full	Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
title_fullStr	Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
title_full_unstemmed	Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
title_sort	novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/aebe5d70bfcb45648364deaaf7debe22
work_keys_str_mv	AT rouholahdordane novelmethodforscalablesynthesisofwollastonitenanoparticleasnanofillerincompositesforpromotionofanticorrosiveproperty AT mohammadmahdidoroodmand novelmethodforscalablesynthesisofwollastonitenanoparticleasnanofillerincompositesforpromotionofanticorrosiveproperty
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Novel method for scalable synthesis of wollastonite nanoparticle as nano-filler in composites for promotion of anti-corrosive property

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