Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye

Due to its excellency and versatility, many synthesis methods and conditions were developed to produce HKUST-1 ([Cu3(BTC)2(H2O)3]n). However, the diversity of HKUST-1 was actually gener...

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Autores principales:	Christian J. Wijaya, Suryadi Ismadji, Hakun W. Aparamarta, Setiyo Gunawan
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	coordination modulation synthesis dye adsorption healthy HKUST-1 metal-organic frameworks optimization Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/b0d61e7dbd324fb4a48aee15373405b0
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spelling	oai:doaj.org-article:b0d61e7dbd324fb4a48aee15373405b02021-11-11T18:26:46ZStatistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye10.3390/molecules262164301420-3049https://doaj.org/article/b0d61e7dbd324fb4a48aee15373405b02021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6430https://doaj.org/toc/1420-3049Due to its excellency and versatility, many synthesis methods and conditions were developed to produce HKUST-1 ([Cu<sub>3</sub>(BTC)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>]<sub>n</sub>). However, the diversity of HKUST-1 was actually generated both in terms of characteristics and morphologies. Hence, the consistency of HKUST-1 characteristics and morphologies needs to be maintained. The statistical analysis and optimization provide features to determine the best synthesis condition. Here, a room-temperature coordination modulation method was proposed to maintain the morphology of HKUST-1 while reducing energy consumption. In addition, response surface methodology (RSM) was used to demonstrate the statistical analysis and optimization of the synthesis of HKUST-1. The molar ratio of ligand to metal, reaction time, and acetic acid concentration were studied to determine their effects on HKUST-1. The optimum HKUST-1 was obtained by the synthesis with a molar ratio of ligand to metal of 0.4703 for 27.2 h using 5% <i>v</i>/<i>v</i> acetic acid concentration. The statistical analysis performed a good agreement with the experimental data and showed the significance of three desired parameters on HKUST-1. The optimum HKUST-1 had the adsorption capacity of 1005.22 mg/g with a removal efficiency of 92.31% towards CV dye. It could be reused up to 5 cycles with insignificant decrease in performance.Christian J. WijayaSuryadi IsmadjiHakun W. AparamartaSetiyo GunawanMDPI AGarticlecoordination modulation synthesisdye adsorptionhealthyHKUST-1metal-organic frameworksoptimizationOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6430, p 6430 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	coordination modulation synthesis dye adsorption healthy HKUST-1 metal-organic frameworks optimization Organic chemistry QD241-441
spellingShingle	coordination modulation synthesis dye adsorption healthy HKUST-1 metal-organic frameworks optimization Organic chemistry QD241-441 Christian J. Wijaya Suryadi Ismadji Hakun W. Aparamarta Setiyo Gunawan Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
description	Due to its excellency and versatility, many synthesis methods and conditions were developed to produce HKUST-1 ([Cu<sub>3</sub>(BTC)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>]<sub>n</sub>). However, the diversity of HKUST-1 was actually generated both in terms of characteristics and morphologies. Hence, the consistency of HKUST-1 characteristics and morphologies needs to be maintained. The statistical analysis and optimization provide features to determine the best synthesis condition. Here, a room-temperature coordination modulation method was proposed to maintain the morphology of HKUST-1 while reducing energy consumption. In addition, response surface methodology (RSM) was used to demonstrate the statistical analysis and optimization of the synthesis of HKUST-1. The molar ratio of ligand to metal, reaction time, and acetic acid concentration were studied to determine their effects on HKUST-1. The optimum HKUST-1 was obtained by the synthesis with a molar ratio of ligand to metal of 0.4703 for 27.2 h using 5% <i>v</i>/<i>v</i> acetic acid concentration. The statistical analysis performed a good agreement with the experimental data and showed the significance of three desired parameters on HKUST-1. The optimum HKUST-1 had the adsorption capacity of 1005.22 mg/g with a removal efficiency of 92.31% towards CV dye. It could be reused up to 5 cycles with insignificant decrease in performance.
format	article
author	Christian J. Wijaya Suryadi Ismadji Hakun W. Aparamarta Setiyo Gunawan
author_facet	Christian J. Wijaya Suryadi Ismadji Hakun W. Aparamarta Setiyo Gunawan
author_sort	Christian J. Wijaya
title	Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
title_short	Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
title_full	Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
title_fullStr	Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
title_full_unstemmed	Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye
title_sort	statistically optimum hkust-1 synthesized by room temperature coordination modulation method for the adsorption of crystal violet dye
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/b0d61e7dbd324fb4a48aee15373405b0
work_keys_str_mv	AT christianjwijaya statisticallyoptimumhkust1synthesizedbyroomtemperaturecoordinationmodulationmethodfortheadsorptionofcrystalvioletdye AT suryadiismadji statisticallyoptimumhkust1synthesizedbyroomtemperaturecoordinationmodulationmethodfortheadsorptionofcrystalvioletdye AT hakunwaparamarta statisticallyoptimumhkust1synthesizedbyroomtemperaturecoordinationmodulationmethodfortheadsorptionofcrystalvioletdye AT setiyogunawan statisticallyoptimumhkust1synthesizedbyroomtemperaturecoordinationmodulationmethodfortheadsorptionofcrystalvioletdye
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Statistically Optimum HKUST-1 Synthesized by Room Temperature Coordination Modulation Method for the Adsorption of Crystal Violet Dye

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