Synthetic exploration of sulfinyl radicals using sulfinyl sulfones

Sulfinyl radicals are an underexplored synthon in organic chemistry due to the fact that they reversibly add to pi systems and undergo homodimerization. Here the authors synthesize sulfonyl sulfones, previously thought to be unstable, and demonstrate their broad use as sulfinyl radical precursors in...

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Autores principales:	Zikun Wang, Zhansong Zhang, Wanjun Zhao, Paramasivam Sivaguru, Giuseppe Zanoni, Yingying Wang, Edward A. Anderson, Xihe Bi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/b0d9211741b94b168c5cb57148b41108
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spelling	oai:doaj.org-article:b0d9211741b94b168c5cb57148b411082021-12-02T15:25:36ZSynthetic exploration of sulfinyl radicals using sulfinyl sulfones10.1038/s41467-021-25593-52041-1723https://doaj.org/article/b0d9211741b94b168c5cb57148b411082021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25593-5https://doaj.org/toc/2041-1723Sulfinyl radicals are an underexplored synthon in organic chemistry due to the fact that they reversibly add to pi systems and undergo homodimerization. Here the authors synthesize sulfonyl sulfones, previously thought to be unstable, and demonstrate their broad use as sulfinyl radical precursors in disulfurizations of alkenes and alkynes.Zikun WangZhansong ZhangWanjun ZhaoParamasivam SivaguruGiuseppe ZanoniYingying WangEdward A. AndersonXihe BiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Zikun Wang Zhansong Zhang Wanjun Zhao Paramasivam Sivaguru Giuseppe Zanoni Yingying Wang Edward A. Anderson Xihe Bi Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
description	Sulfinyl radicals are an underexplored synthon in organic chemistry due to the fact that they reversibly add to pi systems and undergo homodimerization. Here the authors synthesize sulfonyl sulfones, previously thought to be unstable, and demonstrate their broad use as sulfinyl radical precursors in disulfurizations of alkenes and alkynes.
format	article
author	Zikun Wang Zhansong Zhang Wanjun Zhao Paramasivam Sivaguru Giuseppe Zanoni Yingying Wang Edward A. Anderson Xihe Bi
author_facet	Zikun Wang Zhansong Zhang Wanjun Zhao Paramasivam Sivaguru Giuseppe Zanoni Yingying Wang Edward A. Anderson Xihe Bi
author_sort	Zikun Wang
title	Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
title_short	Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
title_full	Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
title_fullStr	Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
title_full_unstemmed	Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
title_sort	synthetic exploration of sulfinyl radicals using sulfinyl sulfones
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/b0d9211741b94b168c5cb57148b41108
work_keys_str_mv	AT zikunwang syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT zhansongzhang syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT wanjunzhao syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT paramasivamsivaguru syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT giuseppezanoni syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT yingyingwang syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT edwardaanderson syntheticexplorationofsulfinylradicalsusingsulfinylsulfones AT xihebi syntheticexplorationofsulfinylradicalsusingsulfinylsulfones
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Synthetic exploration of sulfinyl radicals using sulfinyl sulfones

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