Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness

A composite material of sodium dodecyl benzene sulfonate- (SDBS-) modified maifanite and anhydride-modified Fe@SiO2@PEI (PEI) was used as an adsorbent for the removal of hexavalent chromium (Cr(VI)) and bivalent cadmium (Cd(II)) from groundwater by using column experiments and simulated PRB test. In...

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Autores principales:	Jingqing Gao, Yalin Zhai, Zhenzhen Huang, Peng Ren, Jianlei Gao, Zhijun Chen, Shunling Li
Formato:	article
Lenguaje:	EN
Publicado:	Hindawi - SAGE Publishing 2021
Materias:	Physical and theoretical chemistry QD450-801
Acceso en línea:	https://doaj.org/article/b0dc59537c574111ad47e0a348427819
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spelling	oai:doaj.org-article:b0dc59537c574111ad47e0a3484278192021-11-22T01:11:16ZRemediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness2048-403810.1155/2021/4998706https://doaj.org/article/b0dc59537c574111ad47e0a3484278192021-01-01T00:00:00Zhttp://dx.doi.org/10.1155/2021/4998706https://doaj.org/toc/2048-4038A composite material of sodium dodecyl benzene sulfonate- (SDBS-) modified maifanite and anhydride-modified Fe@SiO2@PEI (PEI) was used as an adsorbent for the removal of hexavalent chromium (Cr(VI)) and bivalent cadmium (Cd(II)) from groundwater by using column experiments and simulated PRB test. In this study, the optimum proportion of SDBS-modified maifanite and anhydride-modified Fe@SiO2@PEI was 5 : 1. In the column experiments, it was found that the penetration time increased with the increase of the initial concentrations (30, 60, and 90 mg/L) and the decrease of the flow rates (5.45, 10.9, and 16.35 mL/min) at an influent pH of 6.5±0.3. It was also obtained that the removal rates of Cr(VI) and Cd(ІІ) reached 99.93% and 99.79% at an initial Cr(VI) and Cd(ІІ) concentration of 30 mg/L with the flow rate of 10.9 mL/min, respectively, at 6 h. Furthermore, excellent removal effectiveness of Cr(VI) and Cd(ІІ) (85.94% and 83.45%, respectively) was still achieved in simulated PRB test at a flow rate of 5.45 mL/min with the heavy metal solution concentration of 5.0±0.5 mg/L (Cr(VI) and Cd(II) concentration were, respectively, 5.0±0.5 mg/L); and the adsorbent had not completely failed by the end of the trial. Yoon-Nelson model was successfully applied to predict the breakthrough curves for the assessment of composite material heavy metal removal performance and was in good agreement with the experimental data of the heavy metal removal efficiency. The strong removal ability of the adsorbent could be attributed to the fact that maifanite with a large diameter can provide support and increase the permeability coefficient and porosity and that zero-valent iron (ZVI) can convert Cr(VI) to Cr(III) and improve the adsorption capacity of maifanite. The obtained results suggested that the novel PRB fillers have great significance for preventing and controlling Cr(VI)/Cd(ІІ)-contaminated groundwater.Jingqing GaoYalin ZhaiZhenzhen HuangPeng RenJianlei GaoZhijun ChenShunling LiHindawi - SAGE PublishingarticlePhysical and theoretical chemistryQD450-801ENAdsorption Science & Technology, Vol 2021 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physical and theoretical chemistry QD450-801
spellingShingle	Physical and theoretical chemistry QD450-801 Jingqing Gao Yalin Zhai Zhenzhen Huang Peng Ren Jianlei Gao Zhijun Chen Shunling Li Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
description	A composite material of sodium dodecyl benzene sulfonate- (SDBS-) modified maifanite and anhydride-modified Fe@SiO2@PEI (PEI) was used as an adsorbent for the removal of hexavalent chromium (Cr(VI)) and bivalent cadmium (Cd(II)) from groundwater by using column experiments and simulated PRB test. In this study, the optimum proportion of SDBS-modified maifanite and anhydride-modified Fe@SiO2@PEI was 5 : 1. In the column experiments, it was found that the penetration time increased with the increase of the initial concentrations (30, 60, and 90 mg/L) and the decrease of the flow rates (5.45, 10.9, and 16.35 mL/min) at an influent pH of 6.5±0.3. It was also obtained that the removal rates of Cr(VI) and Cd(ІІ) reached 99.93% and 99.79% at an initial Cr(VI) and Cd(ІІ) concentration of 30 mg/L with the flow rate of 10.9 mL/min, respectively, at 6 h. Furthermore, excellent removal effectiveness of Cr(VI) and Cd(ІІ) (85.94% and 83.45%, respectively) was still achieved in simulated PRB test at a flow rate of 5.45 mL/min with the heavy metal solution concentration of 5.0±0.5 mg/L (Cr(VI) and Cd(II) concentration were, respectively, 5.0±0.5 mg/L); and the adsorbent had not completely failed by the end of the trial. Yoon-Nelson model was successfully applied to predict the breakthrough curves for the assessment of composite material heavy metal removal performance and was in good agreement with the experimental data of the heavy metal removal efficiency. The strong removal ability of the adsorbent could be attributed to the fact that maifanite with a large diameter can provide support and increase the permeability coefficient and porosity and that zero-valent iron (ZVI) can convert Cr(VI) to Cr(III) and improve the adsorption capacity of maifanite. The obtained results suggested that the novel PRB fillers have great significance for preventing and controlling Cr(VI)/Cd(ІІ)-contaminated groundwater.
format	article
author	Jingqing Gao Yalin Zhai Zhenzhen Huang Peng Ren Jianlei Gao Zhijun Chen Shunling Li
author_facet	Jingqing Gao Yalin Zhai Zhenzhen Huang Peng Ren Jianlei Gao Zhijun Chen Shunling Li
author_sort	Jingqing Gao
title	Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
title_short	Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
title_full	Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
title_fullStr	Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
title_full_unstemmed	Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness
title_sort	remediation of cr(vi)/cd(іі)-contaminated groundwater with simulated permeable reaction barriers filled with composite of sodium dodecyl benzene sulfonate-modified maifanite and anhydride-modified fe@sio2@polyethyleneimine: environmental factors and effectiveness
publisher	Hindawi - SAGE Publishing
publishDate	2021
url	https://doaj.org/article/b0dc59537c574111ad47e0a348427819
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Remediation of Cr(VI)/Cd(ІІ)-Contaminated Groundwater with Simulated Permeable Reaction Barriers Filled with Composite of Sodium Dodecyl Benzene Sulfonate-Modified Maifanite and Anhydride-Modified Fe@SiO2@Polyethyleneimine: Environmental Factors and Effectiveness

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