Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light

Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetyle...

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Autores principales: Chenlu He, Guang Yang, Yan Kuai, Sizhen Shan, Lin Yang, Jingang Hu, Douguo Zhang, Qijin Zhang, Gang Zou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/b1021bc15b0e4c68925d1428f8fbfcad
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spelling oai:doaj.org-article:b1021bc15b0e4c68925d1428f8fbfcad2021-12-02T17:32:03ZDissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light10.1038/s41467-018-07533-y2041-1723https://doaj.org/article/b1021bc15b0e4c68925d1428f8fbfcad2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07533-yhttps://doaj.org/toc/2041-1723Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films.Chenlu HeGuang YangYan KuaiSizhen ShanLin YangJingang HuDouguo ZhangQijin ZhangGang ZouNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Chenlu He
Guang Yang
Yan Kuai
Sizhen Shan
Lin Yang
Jingang Hu
Douguo Zhang
Qijin Zhang
Gang Zou
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
description Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films.
format article
author Chenlu He
Guang Yang
Yan Kuai
Sizhen Shan
Lin Yang
Jingang Hu
Douguo Zhang
Qijin Zhang
Gang Zou
author_facet Chenlu He
Guang Yang
Yan Kuai
Sizhen Shan
Lin Yang
Jingang Hu
Douguo Zhang
Qijin Zhang
Gang Zou
author_sort Chenlu He
title Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
title_short Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
title_full Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
title_fullStr Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
title_full_unstemmed Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
title_sort dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/b1021bc15b0e4c68925d1428f8fbfcad
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