Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetyle...
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Nature Portfolio
2018
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oai:doaj.org-article:b1021bc15b0e4c68925d1428f8fbfcad2021-12-02T17:32:03ZDissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light10.1038/s41467-018-07533-y2041-1723https://doaj.org/article/b1021bc15b0e4c68925d1428f8fbfcad2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07533-yhttps://doaj.org/toc/2041-1723Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films.Chenlu HeGuang YangYan KuaiSizhen ShanLin YangJingang HuDouguo ZhangQijin ZhangGang ZouNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018) |
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Science Q Chenlu He Guang Yang Yan Kuai Sizhen Shan Lin Yang Jingang Hu Douguo Zhang Qijin Zhang Gang Zou Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
description |
Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films. |
format |
article |
author |
Chenlu He Guang Yang Yan Kuai Sizhen Shan Lin Yang Jingang Hu Douguo Zhang Qijin Zhang Gang Zou |
author_facet |
Chenlu He Guang Yang Yan Kuai Sizhen Shan Lin Yang Jingang Hu Douguo Zhang Qijin Zhang Gang Zou |
author_sort |
Chenlu He |
title |
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
title_short |
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
title_full |
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
title_fullStr |
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
title_full_unstemmed |
Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
title_sort |
dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/b1021bc15b0e4c68925d1428f8fbfcad |
work_keys_str_mv |
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_version_ |
1718380448952877056 |