Stereoselective one-pot synthesis of polypropionates

Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrol...

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Autores principales: Guo-Ming Ho, Medel Manuel L. Zulueta, Shang-Cheng Hung
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/b140a1fe9d114e65bbec23b74c8da0f3
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spelling oai:doaj.org-article:b140a1fe9d114e65bbec23b74c8da0f32021-12-02T17:06:12ZStereoselective one-pot synthesis of polypropionates10.1038/s41467-017-00787-y2041-1723https://doaj.org/article/b140a1fe9d114e65bbec23b74c8da0f32017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00787-yhttps://doaj.org/toc/2041-1723Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrolysis and Baeyer–Villiger oxidation.Guo-Ming HoMedel Manuel L. ZuluetaShang-Cheng HungNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Guo-Ming Ho
Medel Manuel L. Zulueta
Shang-Cheng Hung
Stereoselective one-pot synthesis of polypropionates
description Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrolysis and Baeyer–Villiger oxidation.
format article
author Guo-Ming Ho
Medel Manuel L. Zulueta
Shang-Cheng Hung
author_facet Guo-Ming Ho
Medel Manuel L. Zulueta
Shang-Cheng Hung
author_sort Guo-Ming Ho
title Stereoselective one-pot synthesis of polypropionates
title_short Stereoselective one-pot synthesis of polypropionates
title_full Stereoselective one-pot synthesis of polypropionates
title_fullStr Stereoselective one-pot synthesis of polypropionates
title_full_unstemmed Stereoselective one-pot synthesis of polypropionates
title_sort stereoselective one-pot synthesis of polypropionates
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/b140a1fe9d114e65bbec23b74c8da0f3
work_keys_str_mv AT guomingho stereoselectiveonepotsynthesisofpolypropionates
AT medelmanuellzulueta stereoselectiveonepotsynthesisofpolypropionates
AT shangchenghung stereoselectiveonepotsynthesisofpolypropionates
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