Stereoselective one-pot synthesis of polypropionates
Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrol...
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Nature Portfolio
2017
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oai:doaj.org-article:b140a1fe9d114e65bbec23b74c8da0f32021-12-02T17:06:12ZStereoselective one-pot synthesis of polypropionates10.1038/s41467-017-00787-y2041-1723https://doaj.org/article/b140a1fe9d114e65bbec23b74c8da0f32017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00787-yhttps://doaj.org/toc/2041-1723Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrolysis and Baeyer–Villiger oxidation.Guo-Ming HoMedel Manuel L. ZuluetaShang-Cheng HungNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Guo-Ming Ho Medel Manuel L. Zulueta Shang-Cheng Hung Stereoselective one-pot synthesis of polypropionates |
description |
Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrolysis and Baeyer–Villiger oxidation. |
format |
article |
author |
Guo-Ming Ho Medel Manuel L. Zulueta Shang-Cheng Hung |
author_facet |
Guo-Ming Ho Medel Manuel L. Zulueta Shang-Cheng Hung |
author_sort |
Guo-Ming Ho |
title |
Stereoselective one-pot synthesis of polypropionates |
title_short |
Stereoselective one-pot synthesis of polypropionates |
title_full |
Stereoselective one-pot synthesis of polypropionates |
title_fullStr |
Stereoselective one-pot synthesis of polypropionates |
title_full_unstemmed |
Stereoselective one-pot synthesis of polypropionates |
title_sort |
stereoselective one-pot synthesis of polypropionates |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/b140a1fe9d114e65bbec23b74c8da0f3 |
work_keys_str_mv |
AT guomingho stereoselectiveonepotsynthesisofpolypropionates AT medelmanuellzulueta stereoselectiveonepotsynthesisofpolypropionates AT shangchenghung stereoselectiveonepotsynthesisofpolypropionates |
_version_ |
1718381693299064832 |