Microscopic mechanism of biphasic interface relaxation in lithium iron phosphate after delithiation

Improving the performance of Li-ion batteries relies on understanding charging/discharging mechanisms. Here the authors visualize the interfacial structure and composition of a partially delithiated lithium iron phosphate single crystal as a function of time, revealing a mechanism of relaxation.

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Auteurs principaux: Shunsuke Kobayashi, Akihide Kuwabara, Craig A. J. Fisher, Yoshio Ukyo, Yuichi Ikuhara
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/b156964e9e974b7b8b704a5b42051ec2
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Résumé:Improving the performance of Li-ion batteries relies on understanding charging/discharging mechanisms. Here the authors visualize the interfacial structure and composition of a partially delithiated lithium iron phosphate single crystal as a function of time, revealing a mechanism of relaxation.