Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels

Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels

While biological fluoride ion channels display excellent F− conductivity and selectivity, designing synthetic analogues remains highly challenging. Here the authors show that zirconium-based metal–organic frameworks with F− binding sites and sub-1-nanometer channels exhibit ultrahigh F− conductivity...

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Autores principales: Xingya Li, Huacheng Zhang, Peiyao Wang, Jue Hou, Jun Lu, Christopher D. Easton, Xiwang Zhang, Matthew R. Hill, Aaron W. Thornton, Jefferson Zhe Liu, Benny D. Freeman, Anita J. Hill, Lei Jiang, Huanting Wang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/b1e61f0cd75e4bbc937d37ae7a0bd7af
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Sumario:While biological fluoride ion channels display excellent F− conductivity and selectivity, designing synthetic analogues remains highly challenging. Here the authors show that zirconium-based metal–organic frameworks with F− binding sites and sub-1-nanometer channels exhibit ultrahigh F− conductivity and selectivity.

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