Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char

Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to conver...

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Autores principales: M. M. Harussani, Umer Rashid, S. M. Sapuan, Khalina Abdan
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:b1f4ae17ec3b4d2792e1f3fe72da3c722021-11-25T18:49:01ZLow-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char10.3390/polym132239802073-4360https://doaj.org/article/b1f4ae17ec3b4d2792e1f3fe72da3c722021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3980https://doaj.org/toc/2073-4360Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to convert disinfected PP-based isolation gown waste (PP-IG) into an optimised amount of char yields. A batch reactor with a horizontal furnace was used to mediate the thermal decomposition of PP-IG. Enhanced surface area and porosity value of PP-IG derived char were obtained via an optimised slow pyrolysis approach. The results showed that the amount of yielded char was inversely proportional to the temperature. This process relied heavily on the process parameters, especially pyrolytic temperature. Additionally, as the heating rate decreased, as well as longer isothermal residence time, the char yields were increased. Optimised temperature for maximum char yields was recorded. The enhanced SBET values for the char and its pore volume were collected, ~24 m<sup>2</sup> g<sup>−1</sup> and ~0.08 cm<sup>3</sup> g<sup>−1</sup>, respectively. The char obtained at higher temperatures display higher volatilisation and carbonisation. These findings are beneficial for the utilisation of this pyrolysis model in plastic waste management and conversion of PP-IG waste into char for further activated carbon and fuel briquettes applications, with the enhanced char yields, amidst the COVID-19 pandemic.M. M. HarussaniUmer RashidS. M. SapuanKhalina AbdanMDPI AGarticleslow pyrolysisCOVID-19 isolation gownpolypropylenecharpyrolysis parametersOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3980, p 3980 (2021)
institution DOAJ
collection DOAJ
language EN
topic slow pyrolysis
COVID-19 isolation gown
polypropylene
char
pyrolysis parameters
Organic chemistry
QD241-441
spellingShingle slow pyrolysis
COVID-19 isolation gown
polypropylene
char
pyrolysis parameters
Organic chemistry
QD241-441
M. M. Harussani
Umer Rashid
S. M. Sapuan
Khalina Abdan
Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
description Yields of carbonaceous char with a high surface area were enhanced by decreasing the temperature to improve the conversion of hazardous plastic polypropylene (PP), the major component in abundantly used isolation gowns. This study applied pyrolysis with different low pyrolytic temperatures to convert disinfected PP-based isolation gown waste (PP-IG) into an optimised amount of char yields. A batch reactor with a horizontal furnace was used to mediate the thermal decomposition of PP-IG. Enhanced surface area and porosity value of PP-IG derived char were obtained via an optimised slow pyrolysis approach. The results showed that the amount of yielded char was inversely proportional to the temperature. This process relied heavily on the process parameters, especially pyrolytic temperature. Additionally, as the heating rate decreased, as well as longer isothermal residence time, the char yields were increased. Optimised temperature for maximum char yields was recorded. The enhanced SBET values for the char and its pore volume were collected, ~24 m<sup>2</sup> g<sup>−1</sup> and ~0.08 cm<sup>3</sup> g<sup>−1</sup>, respectively. The char obtained at higher temperatures display higher volatilisation and carbonisation. These findings are beneficial for the utilisation of this pyrolysis model in plastic waste management and conversion of PP-IG waste into char for further activated carbon and fuel briquettes applications, with the enhanced char yields, amidst the COVID-19 pandemic.
format article
author M. M. Harussani
Umer Rashid
S. M. Sapuan
Khalina Abdan
author_facet M. M. Harussani
Umer Rashid
S. M. Sapuan
Khalina Abdan
author_sort M. M. Harussani
title Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
title_short Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
title_full Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
title_fullStr Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
title_full_unstemmed Low-Temperature Thermal Degradation of Disinfected COVID-19 Non-Woven Polypropylene—Based Isolation Gown Wastes into Carbonaceous Char
title_sort low-temperature thermal degradation of disinfected covid-19 non-woven polypropylene—based isolation gown wastes into carbonaceous char
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/b1f4ae17ec3b4d2792e1f3fe72da3c72
work_keys_str_mv AT mmharussani lowtemperaturethermaldegradationofdisinfectedcovid19nonwovenpolypropylenebasedisolationgownwastesintocarbonaceouschar
AT umerrashid lowtemperaturethermaldegradationofdisinfectedcovid19nonwovenpolypropylenebasedisolationgownwastesintocarbonaceouschar
AT smsapuan lowtemperaturethermaldegradationofdisinfectedcovid19nonwovenpolypropylenebasedisolationgownwastesintocarbonaceouschar
AT khalinaabdan lowtemperaturethermaldegradationofdisinfectedcovid19nonwovenpolypropylenebasedisolationgownwastesintocarbonaceouschar
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