Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine

The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported...

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Autor principal:	Alyaa Esam Mahdi
Formato:	article
Lenguaje:	EN
Publicado:	Al-Khwarizmi College of Engineering – University of Baghdad 2013
Materias:	Schiff Base Polymeric Complexes Spectroscopic Methods Divalent Metals Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/b35db8d78abc4caf800404ac23f2c797
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spelling	oai:doaj.org-article:b35db8d78abc4caf800404ac23f2c7972021-12-02T04:42:05ZSpectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine1818-11712312-0789https://doaj.org/article/b35db8d78abc4caf800404ac23f2c7972013-12-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/183https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H2O)2]. Alyaa Esam MahdiAl-Khwarizmi College of Engineering – University of BaghdadarticleSchiff BasePolymeric ComplexesSpectroscopic MethodsDivalent MetalsChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 9, Iss 4 (2013)
institution	DOAJ
collection	DOAJ
language	EN
topic	Schiff Base Polymeric Complexes Spectroscopic Methods Divalent Metals Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	Schiff Base Polymeric Complexes Spectroscopic Methods Divalent Metals Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 Alyaa Esam Mahdi Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
description	The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H2O)2].
format	article
author	Alyaa Esam Mahdi
author_facet	Alyaa Esam Mahdi
author_sort	Alyaa Esam Mahdi
title	Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
title_short	Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
title_full	Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
title_fullStr	Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
title_full_unstemmed	Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine
title_sort	spectral study of pt (ii), cr (ii) polymeric complexes of the ligand n- crotonyl -2- hydroxy-phenylazomethine
publisher	Al-Khwarizmi College of Engineering – University of Baghdad
publishDate	2013
url	https://doaj.org/article/b35db8d78abc4caf800404ac23f2c797
work_keys_str_mv	AT alyaaesammahdi spectralstudyofptiicriipolymericcomplexesoftheligandncrotonyl2hydroxyphenylazomethine
_version_	1718401145378963456

Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the Ligand N- Crotonyl -2- Hydroxy-Phenylazomethine

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