Autocatalytic photoredox Chan-Lam coupling of free diaryl sulfoximines with arylboronic acids

N-Arylation of NH-diaryl sulfoximines faces synthetic challenges among reported methods. Here, the authors present a mild copper-catalyzed photoredox dehydrogenative Chan-Lam coupling of free diaryl sulfoximines and arylboronic acids via an auto-catalytic process.

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Detalles Bibliográficos
Autores principales: Cong Wang, Hui Zhang, Lucille A. Wells, Tian Liu, Tingting Meng, Qingchao Liu, Patrick J. Walsh, Marisa C. Kozlowski, Tiezheng Jia
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/b3b7c585ed974409961529e6bcd67547
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Sumario:N-Arylation of NH-diaryl sulfoximines faces synthetic challenges among reported methods. Here, the authors present a mild copper-catalyzed photoredox dehydrogenative Chan-Lam coupling of free diaryl sulfoximines and arylboronic acids via an auto-catalytic process.