Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones

Gamma-butyrolactones are widespread in Nature, however direct catalytic methods to access them are limited. Here, the authors report a gold-catalyzed cycloisomerization of allenoic acids to acces γ-butyrolactones and apply it to the asymmetric synthesis of xestospongienes E, F, G, and H and other na...

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Autores principales:	Jing Zhou, Chunling Fu, Shengming Ma
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/b43cbcd82d9b4adeaf1c16bd74a89588
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spelling	oai:doaj.org-article:b43cbcd82d9b4adeaf1c16bd74a895882021-12-02T17:32:16ZGold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones10.1038/s41467-018-03894-62041-1723https://doaj.org/article/b43cbcd82d9b4adeaf1c16bd74a895882018-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03894-6https://doaj.org/toc/2041-1723Gamma-butyrolactones are widespread in Nature, however direct catalytic methods to access them are limited. Here, the authors report a gold-catalyzed cycloisomerization of allenoic acids to acces γ-butyrolactones and apply it to the asymmetric synthesis of xestospongienes E, F, G, and H and other naturally occurring lactones.Jing ZhouChunling FuShengming MaNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jing Zhou Chunling Fu Shengming Ma Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
description	Gamma-butyrolactones are widespread in Nature, however direct catalytic methods to access them are limited. Here, the authors report a gold-catalyzed cycloisomerization of allenoic acids to acces γ-butyrolactones and apply it to the asymmetric synthesis of xestospongienes E, F, G, and H and other naturally occurring lactones.
format	article
author	Jing Zhou Chunling Fu Shengming Ma
author_facet	Jing Zhou Chunling Fu Shengming Ma
author_sort	Jing Zhou
title	Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
title_short	Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
title_full	Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
title_fullStr	Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
title_full_unstemmed	Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
title_sort	gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/b43cbcd82d9b4adeaf1c16bd74a89588
work_keys_str_mv	AT jingzhou goldcatalyzedstereoselectivecycloisomerizationofallenoicacidsfortwotypesofcommonnaturalgbutyrolactones AT chunlingfu goldcatalyzedstereoselectivecycloisomerizationofallenoicacidsfortwotypesofcommonnaturalgbutyrolactones AT shengmingma goldcatalyzedstereoselectivecycloisomerizationofallenoicacidsfortwotypesofcommonnaturalgbutyrolactones
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Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones

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