Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer

Abstract A proton exchange membrane (PEM) is one of the most critical and expensive components in a dual‐chamber microbial fuel cell (MFC) that separates the anode and cathode chambers. The novel macroporous kaolin earthenware coated with polybenzimidazole (NKE‐PBI) fabricated in this study could be...

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Autores principales: Siti Mariam Daud, Mimi Hani Abu Bakar, Wan Ramli Wan Daud, Byung Hong Kim, Jamaliah Md Jahim, Andanastuti Muchtar, Mahendra Roa Somalu, Pak Hoe Lee, Peer Mohamed Abdul
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Publicado: Wiley 2021
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spelling oai:doaj.org-article:b498ddbce4e74ffc9ff90612273000ea2021-12-02T05:24:30ZImprovement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer2050-050510.1002/ese3.988https://doaj.org/article/b498ddbce4e74ffc9ff90612273000ea2021-12-01T00:00:00Zhttps://doi.org/10.1002/ese3.988https://doaj.org/toc/2050-0505Abstract A proton exchange membrane (PEM) is one of the most critical and expensive components in a dual‐chamber microbial fuel cell (MFC) that separates the anode and cathode chambers. The novel macroporous kaolin earthenware coated with polybenzimidazole (NKE‐PBI) fabricated in this study could become an alternative to PEM membranes. Briefly, PBI powder was dissolved in dimethylacetamide. Thereafter, NKE was fabricated at different porosities (10%, 20%, and 30%) using different starch powder volumes, which acted as pore‐forming agents. The NKE‐PBI with 30 vol% starch powder content produced the highest power output of 2450 ± 25 mW m−2 (10.50 A m−2) and internal resistance of 71 ± 19 Ω under batch mode operation. The MFC–PEM reactor generated the lowest power output at the highest internal resistance of up to 1300 ± 15 mW m−2 (3.7 A m−2) and 313 ± 16 Ω, respectively. In this study, the nonselective porous NKE coated with PBI membranes improved proton conduction activity and displayed comparable power performance with that of Nafion 117 in a dual‐chambered MFC. Therefore, a porous earthenware membrane coated with a proton conductor could become a potential separator in a scaled‐up MFC system for commercialization.Siti Mariam DaudMimi Hani Abu BakarWan Ramli Wan DaudByung Hong KimJamaliah Md JahimAndanastuti MuchtarMahendra Roa SomaluPak Hoe LeePeer Mohamed AbdulWileyarticlemicrobial fuel cell technologynovel kaolin earthenwarepolybenzimidazoleproton conductorproton exchange membraneTechnologyTScienceQENEnergy Science & Engineering, Vol 9, Iss 12, Pp 2342-2353 (2021)
institution DOAJ
collection DOAJ
language EN
topic microbial fuel cell technology
novel kaolin earthenware
polybenzimidazole
proton conductor
proton exchange membrane
Technology
T
Science
Q
spellingShingle microbial fuel cell technology
novel kaolin earthenware
polybenzimidazole
proton conductor
proton exchange membrane
Technology
T
Science
Q
Siti Mariam Daud
Mimi Hani Abu Bakar
Wan Ramli Wan Daud
Byung Hong Kim
Jamaliah Md Jahim
Andanastuti Muchtar
Mahendra Roa Somalu
Pak Hoe Lee
Peer Mohamed Abdul
Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
description Abstract A proton exchange membrane (PEM) is one of the most critical and expensive components in a dual‐chamber microbial fuel cell (MFC) that separates the anode and cathode chambers. The novel macroporous kaolin earthenware coated with polybenzimidazole (NKE‐PBI) fabricated in this study could become an alternative to PEM membranes. Briefly, PBI powder was dissolved in dimethylacetamide. Thereafter, NKE was fabricated at different porosities (10%, 20%, and 30%) using different starch powder volumes, which acted as pore‐forming agents. The NKE‐PBI with 30 vol% starch powder content produced the highest power output of 2450 ± 25 mW m−2 (10.50 A m−2) and internal resistance of 71 ± 19 Ω under batch mode operation. The MFC–PEM reactor generated the lowest power output at the highest internal resistance of up to 1300 ± 15 mW m−2 (3.7 A m−2) and 313 ± 16 Ω, respectively. In this study, the nonselective porous NKE coated with PBI membranes improved proton conduction activity and displayed comparable power performance with that of Nafion 117 in a dual‐chambered MFC. Therefore, a porous earthenware membrane coated with a proton conductor could become a potential separator in a scaled‐up MFC system for commercialization.
format article
author Siti Mariam Daud
Mimi Hani Abu Bakar
Wan Ramli Wan Daud
Byung Hong Kim
Jamaliah Md Jahim
Andanastuti Muchtar
Mahendra Roa Somalu
Pak Hoe Lee
Peer Mohamed Abdul
author_facet Siti Mariam Daud
Mimi Hani Abu Bakar
Wan Ramli Wan Daud
Byung Hong Kim
Jamaliah Md Jahim
Andanastuti Muchtar
Mahendra Roa Somalu
Pak Hoe Lee
Peer Mohamed Abdul
author_sort Siti Mariam Daud
title Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
title_short Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
title_full Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
title_fullStr Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
title_full_unstemmed Improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
title_sort improvement of microbial fuel cell performance using novel kaolin earthenware membrane coated with a polybenzimidazole layer
publisher Wiley
publishDate 2021
url https://doaj.org/article/b498ddbce4e74ffc9ff90612273000ea
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