Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content

Pore structure is a major factor affecting the storage space and oil-bearing properties of shales. Mineralogy, organic matter content, and thermal evolution complicate the pore structures of lacustrine shales. In this study, the porosity evolution of organic-matter-rich shales from the Cretaceous Ne...

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Autores principales: Xiaohua Jiang, Songtao Wu, Lianhua Hou, Jinyou Zhang, Modi Guan, Fulin Zhai, Jinhao Guo, Ling Su, Fengrong Liao, Lihua Ding
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Publicado: Frontiers Media S.A. 2021
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Acceso en línea:https://doaj.org/article/b4de738d88344a0bac049e433b40c01c
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spelling oai:doaj.org-article:b4de738d88344a0bac049e433b40c01c2021-11-30T15:44:32ZPorosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content2296-646310.3389/feart.2021.766093https://doaj.org/article/b4de738d88344a0bac049e433b40c01c2021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/feart.2021.766093/fullhttps://doaj.org/toc/2296-6463Pore structure is a major factor affecting the storage space and oil-bearing properties of shales. Mineralogy, organic matter content, and thermal evolution complicate the pore structures of lacustrine shales. In this study, the porosity evolution of organic-matter-rich shales from the Cretaceous Nenjiang Formation in the Songliao Basin, Northeast China, are investigated using thermal simulation experiments and in-situ scanning electron microscope analysis. Three findings were obtained as follows: 1) The pore system of shales from the Nenjiang Formation is dominated by inter-granular dissolution pores of plagioclase and intra-granular pores of illite-smectite mixed layers. Few organic-matter pores are observed. 2) New pores developing during thermal evolution are primarily organic matter pores and clay mineral pores, with diameters greater than 18 nm. Clay mineral pores with diameters of 18–50 nm are the principal contributors to porosity at temperatures between the low maturity stage and the oil-generation window, and organic matter pores with diameters of greater than 50 nm comprise the majority of pores generated between the gas-generation window and the high-/over-mature stages. 3) Porosity increases continuously with maturity, and the pore system varies at different maturity stages. Porosity evolution is controlled by illite content and organic matter abundance. Total pore volume correlates positively with illite content but negatively with organic matter abundance. These findings could provide guidance on shale oil evaluation in the Songliao Basin and assist in the ‘sweet-spotting’ of lacustrine shale systems across China.Xiaohua JiangXiaohua JiangXiaohua JiangSongtao WuSongtao WuSongtao WuLianhua HouLianhua HouJinyou ZhangModi GuanModi GuanFulin ZhaiFulin ZhaiJinhao GuoLing SuLing SuLing SuFengrong LiaoFengrong LiaoFengrong LiaoLihua DingLihua DingFrontiers Media S.A.articleshale oilfine-grained depositionunconventional oil and gasnano pore-throat systemin-situ conversionScienceQENFrontiers in Earth Science, Vol 9 (2021)
institution DOAJ
collection DOAJ
language EN
topic shale oil
fine-grained deposition
unconventional oil and gas
nano pore-throat system
in-situ conversion
Science
Q
spellingShingle shale oil
fine-grained deposition
unconventional oil and gas
nano pore-throat system
in-situ conversion
Science
Q
Xiaohua Jiang
Xiaohua Jiang
Xiaohua Jiang
Songtao Wu
Songtao Wu
Songtao Wu
Lianhua Hou
Lianhua Hou
Jinyou Zhang
Modi Guan
Modi Guan
Fulin Zhai
Fulin Zhai
Jinhao Guo
Ling Su
Ling Su
Ling Su
Fengrong Liao
Fengrong Liao
Fengrong Liao
Lihua Ding
Lihua Ding
Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
description Pore structure is a major factor affecting the storage space and oil-bearing properties of shales. Mineralogy, organic matter content, and thermal evolution complicate the pore structures of lacustrine shales. In this study, the porosity evolution of organic-matter-rich shales from the Cretaceous Nenjiang Formation in the Songliao Basin, Northeast China, are investigated using thermal simulation experiments and in-situ scanning electron microscope analysis. Three findings were obtained as follows: 1) The pore system of shales from the Nenjiang Formation is dominated by inter-granular dissolution pores of plagioclase and intra-granular pores of illite-smectite mixed layers. Few organic-matter pores are observed. 2) New pores developing during thermal evolution are primarily organic matter pores and clay mineral pores, with diameters greater than 18 nm. Clay mineral pores with diameters of 18–50 nm are the principal contributors to porosity at temperatures between the low maturity stage and the oil-generation window, and organic matter pores with diameters of greater than 50 nm comprise the majority of pores generated between the gas-generation window and the high-/over-mature stages. 3) Porosity increases continuously with maturity, and the pore system varies at different maturity stages. Porosity evolution is controlled by illite content and organic matter abundance. Total pore volume correlates positively with illite content but negatively with organic matter abundance. These findings could provide guidance on shale oil evaluation in the Songliao Basin and assist in the ‘sweet-spotting’ of lacustrine shale systems across China.
format article
author Xiaohua Jiang
Xiaohua Jiang
Xiaohua Jiang
Songtao Wu
Songtao Wu
Songtao Wu
Lianhua Hou
Lianhua Hou
Jinyou Zhang
Modi Guan
Modi Guan
Fulin Zhai
Fulin Zhai
Jinhao Guo
Ling Su
Ling Su
Ling Su
Fengrong Liao
Fengrong Liao
Fengrong Liao
Lihua Ding
Lihua Ding
author_facet Xiaohua Jiang
Xiaohua Jiang
Xiaohua Jiang
Songtao Wu
Songtao Wu
Songtao Wu
Lianhua Hou
Lianhua Hou
Jinyou Zhang
Modi Guan
Modi Guan
Fulin Zhai
Fulin Zhai
Jinhao Guo
Ling Su
Ling Su
Ling Su
Fengrong Liao
Fengrong Liao
Fengrong Liao
Lihua Ding
Lihua Ding
author_sort Xiaohua Jiang
title Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
title_short Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
title_full Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
title_fullStr Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
title_full_unstemmed Porosity Evolution In Lacustrine Organic-Matter-Rich Shales With High Claly Minerals Content
title_sort porosity evolution in lacustrine organic-matter-rich shales with high claly minerals content
publisher Frontiers Media S.A.
publishDate 2021
url https://doaj.org/article/b4de738d88344a0bac049e433b40c01c
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