Filming ultrafast roaming-mediated isomerization of bismuth triiodide in solution

The roaming reaction is a common process in the gas phase and in solution, but observation of the involved atomic movements has been challenging. The authors, using femtosecond time-resolved X-ray liquidography, resolve the detailed structural dynamics at the onset of a roaming reaction in the photo...

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Autores principales: Eun Hyuk Choi, Jong Goo Kim, Jungmin Kim, Hosung Ki, Yunbeom Lee, Seonggon Lee, Kihwan Yoon, Joonghan Kim, Jeongho Kim, Hyotcherl Ihee
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/b586016b08314587a77fda0a82406686
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Sumario:The roaming reaction is a common process in the gas phase and in solution, but observation of the involved atomic movements has been challenging. The authors, using femtosecond time-resolved X-ray liquidography, resolve the detailed structural dynamics at the onset of a roaming reaction in the photoinduced isomerization of BiI3 in solution.