Practical and stereoselective electrocatalytic 1,2-diamination of alkenes

Methods to prepare 1,2-diamines are desirable due the importance of these compounds as drug scaffolds and organic ligands for metals. Here, the authors report an electrochemical metal-free 1,2- diamination of aryl alkenes with sulfamides to 1,2-diamines with excellent diastereoselectivity.

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Auteurs principaux:	Chen-Yan Cai, Xiao-Min Shu, Hai-Chao Xu
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2019
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/b59a4a032dcb465182ca19b66a7eb4a3
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spelling	oai:doaj.org-article:b59a4a032dcb465182ca19b66a7eb4a32021-12-02T14:38:59ZPractical and stereoselective electrocatalytic 1,2-diamination of alkenes10.1038/s41467-019-13024-52041-1723https://doaj.org/article/b59a4a032dcb465182ca19b66a7eb4a32019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13024-5https://doaj.org/toc/2041-1723Methods to prepare 1,2-diamines are desirable due the importance of these compounds as drug scaffolds and organic ligands for metals. Here, the authors report an electrochemical metal-free 1,2- diamination of aryl alkenes with sulfamides to 1,2-diamines with excellent diastereoselectivity.Chen-Yan CaiXiao-Min ShuHai-Chao XuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chen-Yan Cai Xiao-Min Shu Hai-Chao Xu Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
description	Methods to prepare 1,2-diamines are desirable due the importance of these compounds as drug scaffolds and organic ligands for metals. Here, the authors report an electrochemical metal-free 1,2- diamination of aryl alkenes with sulfamides to 1,2-diamines with excellent diastereoselectivity.
format	article
author	Chen-Yan Cai Xiao-Min Shu Hai-Chao Xu
author_facet	Chen-Yan Cai Xiao-Min Shu Hai-Chao Xu
author_sort	Chen-Yan Cai
title	Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
title_short	Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
title_full	Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
title_fullStr	Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
title_full_unstemmed	Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
title_sort	practical and stereoselective electrocatalytic 1,2-diamination of alkenes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/b59a4a032dcb465182ca19b66a7eb4a3
work_keys_str_mv	AT chenyancai practicalandstereoselectiveelectrocatalytic12diaminationofalkenes AT xiaominshu practicalandstereoselectiveelectrocatalytic12diaminationofalkenes AT haichaoxu practicalandstereoselectiveelectrocatalytic12diaminationofalkenes
_version_	1718390791460618240

Practical and stereoselective electrocatalytic 1,2-diamination of alkenes

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