Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
Methods to prepare 1,2-diamines are desirable due the importance of these compounds as drug scaffolds and organic ligands for metals. Here, the authors report an electrochemical metal-free 1,2- diamination of aryl alkenes with sulfamides to 1,2-diamines with excellent diastereoselectivity.
Guardado en:
Autores principales: | Chen-Yan Cai, Xiao-Min Shu, Hai-Chao Xu |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/b59a4a032dcb465182ca19b66a7eb4a3 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
por: Chen-Yan Cai, et al.
Publicado: (2018) -
Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles
por: Yan-Yun Liu, et al.
Publicado: (2017) -
Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination
por: He-Yuan Bai, et al.
Publicado: (2019) -
Synthesis of chiral anti-1,2-diamine derivatives through copper(I)-catalyzed asymmetric α-addition of ketimines to aldimines
por: Xu-Cheng Gan, et al.
Publicado: (2020) -
Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
por: Xu Chen, et al.
Publicado: (2018)