Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles
Abstract Mixed-metal oxide nanoparticles have attracted great scientific interest since they find applications in many fields. However, the synthesis of size-controlled and composition-tuned mixed-metal oxide nanoparticles is a great challenge that complicates their study for practical application....
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oai:doaj.org-article:b5a9e84cdf8d4858bd6e0daec2a497be2021-11-08T11:13:59ZPreparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles10.1186/s11671-021-03619-71556-276Xhttps://doaj.org/article/b5a9e84cdf8d4858bd6e0daec2a497be2021-11-01T00:00:00Zhttps://doi.org/10.1186/s11671-021-03619-7https://doaj.org/toc/1556-276XAbstract Mixed-metal oxide nanoparticles have attracted great scientific interest since they find applications in many fields. However, the synthesis of size-controlled and composition-tuned mixed-metal oxide nanoparticles is a great challenge that complicates their study for practical application. In this study, Co-doped FeMn2O4 nanoparticles were synthesized by the solvothermal method in which the crystallization was carried out under autogenous pressure at temperatures of 190 °C for 24 h. The influence of Co doping on the evolution of the structural and magnetic properties was investigated by various methods. It was found from XRD data that crystallite size decreases from 9.1 to 4.4 nm with the increase in Co content, which is in good agreement with the results of TEM. Based on the results of magnetic measurements, it was found that the saturation magnetization first increases with an increase in the cobalt content and reaches its maximum value at x = 0.4, and a further increase in x leads to a decrease in the saturation magnetization. The influence of cation redistribution on the observed changes has been discussed.Aleksandr A. SpivakovChun-Rong LinEn-Szu LinYing-Zhen ChenYaw-Teng TsengSpringerOpenarticleFeMn2O4 nanoparticlesSpinel ferriteCobalt dopingMagnetic propertiesMaterials of engineering and construction. Mechanics of materialsTA401-492ENNanoscale Research Letters, Vol 16, Iss 1, Pp 1-7 (2021) |
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FeMn2O4 nanoparticles Spinel ferrite Cobalt doping Magnetic properties Materials of engineering and construction. Mechanics of materials TA401-492 |
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FeMn2O4 nanoparticles Spinel ferrite Cobalt doping Magnetic properties Materials of engineering and construction. Mechanics of materials TA401-492 Aleksandr A. Spivakov Chun-Rong Lin En-Szu Lin Ying-Zhen Chen Yaw-Teng Tseng Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
description |
Abstract Mixed-metal oxide nanoparticles have attracted great scientific interest since they find applications in many fields. However, the synthesis of size-controlled and composition-tuned mixed-metal oxide nanoparticles is a great challenge that complicates their study for practical application. In this study, Co-doped FeMn2O4 nanoparticles were synthesized by the solvothermal method in which the crystallization was carried out under autogenous pressure at temperatures of 190 °C for 24 h. The influence of Co doping on the evolution of the structural and magnetic properties was investigated by various methods. It was found from XRD data that crystallite size decreases from 9.1 to 4.4 nm with the increase in Co content, which is in good agreement with the results of TEM. Based on the results of magnetic measurements, it was found that the saturation magnetization first increases with an increase in the cobalt content and reaches its maximum value at x = 0.4, and a further increase in x leads to a decrease in the saturation magnetization. The influence of cation redistribution on the observed changes has been discussed. |
format |
article |
author |
Aleksandr A. Spivakov Chun-Rong Lin En-Szu Lin Ying-Zhen Chen Yaw-Teng Tseng |
author_facet |
Aleksandr A. Spivakov Chun-Rong Lin En-Szu Lin Ying-Zhen Chen Yaw-Teng Tseng |
author_sort |
Aleksandr A. Spivakov |
title |
Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
title_short |
Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
title_full |
Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
title_fullStr |
Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
title_full_unstemmed |
Preparation and Magnetic Properties of Cobalt-Doped FeMn2O4 Spinel Nanoparticles |
title_sort |
preparation and magnetic properties of cobalt-doped femn2o4 spinel nanoparticles |
publisher |
SpringerOpen |
publishDate |
2021 |
url |
https://doaj.org/article/b5a9e84cdf8d4858bd6e0daec2a497be |
work_keys_str_mv |
AT aleksandraspivakov preparationandmagneticpropertiesofcobaltdopedfemn2o4spinelnanoparticles AT chunronglin preparationandmagneticpropertiesofcobaltdopedfemn2o4spinelnanoparticles AT enszulin preparationandmagneticpropertiesofcobaltdopedfemn2o4spinelnanoparticles AT yingzhenchen preparationandmagneticpropertiesofcobaltdopedfemn2o4spinelnanoparticles AT yawtengtseng preparationandmagneticpropertiesofcobaltdopedfemn2o4spinelnanoparticles |
_version_ |
1718442367528206336 |