Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode

Hesperidin (HESP) is a plant bioflavonoid found in various nutritional and medicinal products. Many of its multiple health benefits rely on the compound’s antioxidant ability, which is due to the presence of oxidizable hydroxyl groups in its structure. Therefore, the present study aimed to investiga...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Iulia Gabriela David, Nimet Numan, Mihaela Buleandră, Dana-Elena Popa, Simona Carmen Lițescu, Sorin Riga, Adela Magdalena Ciobanu
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	pencil graphite electrode voltammetry hesperidin bioflavonoids antioxidant dietary supplements Biochemistry QD415-436
Acceso en línea:	https://doaj.org/article/b682389130d34e8a901efc27ebc97dda
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:b682389130d34e8a901efc27ebc97dda
record_format	dspace
spelling	oai:doaj.org-article:b682389130d34e8a901efc27ebc97dda2021-11-25T17:13:43ZRapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode10.3390/chemosensors91103232227-9040https://doaj.org/article/b682389130d34e8a901efc27ebc97dda2021-11-01T00:00:00Zhttps://www.mdpi.com/2227-9040/9/11/323https://doaj.org/toc/2227-9040Hesperidin (HESP) is a plant bioflavonoid found in various nutritional and medicinal products. Many of its multiple health benefits rely on the compound’s antioxidant ability, which is due to the presence of oxidizable hydroxyl groups in its structure. Therefore, the present study aimed to investigate the electrochemical behavior of HESP at a cheap, disposable pencil graphite electrode (PGE) in order to develop rapid and simple voltammetric methods for its quantification. Cyclic voltammetric investigations emphasized a complex electrochemical behavior of HESP. The influence of the electrode material, solution stability, supporting electrolyte pH, and nature were examined. HESP main irreversible, diffusion-controlled oxidation signal obtained at H type PGE in Britton Robinson buffer pH 1.81 was exploited for the development of a differential pulse voltammetry (DPV) quantitative analysis method. The quasi-reversible, adsorption-controlled reduction peak was used for HESP quantification by differential pulse adsorptive stripping voltammetry (DPAdSV). The linear ranges of DPV and DPAdSV were 1.00 × 10<sup>−7</sup>–1.20 × 10<sup>−5</sup> and 5.00 × 10<sup>−8</sup>–1.00 × 10<sup>−6</sup> mol/L with detection limits of 8.58 × 10<sup>−8</sup> and 1.90 × 10<sup>−8</sup> mol/L HESP, respectively. The DPV method was applied for the assessment of dietary supplements bioflavonoid content, expressed as mg HESP.Iulia Gabriela DavidNimet NumanMihaela BuleandrăDana-Elena PopaSimona Carmen LițescuSorin RigaAdela Magdalena CiobanuMDPI AGarticlepencil graphite electrodevoltammetryhesperidinbioflavonoidsantioxidantdietary supplementsBiochemistryQD415-436ENChemosensors, Vol 9, Iss 323, p 323 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	pencil graphite electrode voltammetry hesperidin bioflavonoids antioxidant dietary supplements Biochemistry QD415-436
spellingShingle	pencil graphite electrode voltammetry hesperidin bioflavonoids antioxidant dietary supplements Biochemistry QD415-436 Iulia Gabriela David Nimet Numan Mihaela Buleandră Dana-Elena Popa Simona Carmen Lițescu Sorin Riga Adela Magdalena Ciobanu Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
description	Hesperidin (HESP) is a plant bioflavonoid found in various nutritional and medicinal products. Many of its multiple health benefits rely on the compound’s antioxidant ability, which is due to the presence of oxidizable hydroxyl groups in its structure. Therefore, the present study aimed to investigate the electrochemical behavior of HESP at a cheap, disposable pencil graphite electrode (PGE) in order to develop rapid and simple voltammetric methods for its quantification. Cyclic voltammetric investigations emphasized a complex electrochemical behavior of HESP. The influence of the electrode material, solution stability, supporting electrolyte pH, and nature were examined. HESP main irreversible, diffusion-controlled oxidation signal obtained at H type PGE in Britton Robinson buffer pH 1.81 was exploited for the development of a differential pulse voltammetry (DPV) quantitative analysis method. The quasi-reversible, adsorption-controlled reduction peak was used for HESP quantification by differential pulse adsorptive stripping voltammetry (DPAdSV). The linear ranges of DPV and DPAdSV were 1.00 × 10<sup>−7</sup>–1.20 × 10<sup>−5</sup> and 5.00 × 10<sup>−8</sup>–1.00 × 10<sup>−6</sup> mol/L with detection limits of 8.58 × 10<sup>−8</sup> and 1.90 × 10<sup>−8</sup> mol/L HESP, respectively. The DPV method was applied for the assessment of dietary supplements bioflavonoid content, expressed as mg HESP.
format	article
author	Iulia Gabriela David Nimet Numan Mihaela Buleandră Dana-Elena Popa Simona Carmen Lițescu Sorin Riga Adela Magdalena Ciobanu
author_facet	Iulia Gabriela David Nimet Numan Mihaela Buleandră Dana-Elena Popa Simona Carmen Lițescu Sorin Riga Adela Magdalena Ciobanu
author_sort	Iulia Gabriela David
title	Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
title_short	Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
title_full	Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
title_fullStr	Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
title_full_unstemmed	Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode
title_sort	rapid voltammetric screening method for the assessment of bioflavonoid content using the disposable bare pencil graphite electrode
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/b682389130d34e8a901efc27ebc97dda
work_keys_str_mv	AT iuliagabrieladavid rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT nimetnuman rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT mihaelabuleandra rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT danaelenapopa rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT simonacarmenlitescu rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT sorinriga rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode AT adelamagdalenaciobanu rapidvoltammetricscreeningmethodfortheassessmentofbioflavonoidcontentusingthedisposablebarepencilgraphiteelectrode
_version_	1718412613801476096

Rapid Voltammetric Screening Method for the Assessment of Bioflavonoid Content Using the Disposable Bare Pencil Graphite Electrode

Ejemplares similares