Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond

Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is play...

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Autores principales: Fupin Liu, Georgios Velkos, Denis S. Krylov, Lukas Spree, Michal Zalibera, Rajyavardhan Ray, Nataliya A. Samoylova, Chia-Hsiang Chen, Marco Rosenkranz, Sandra Schiemenz, Frank Ziegs, Konstantin Nenkov, Aram Kostanyan, Thomas Greber, Anja U. B. Wolter, Manuel Richter, Bernd Büchner, Stanislav M. Avdoshenko, Alexey A. Popov
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/b6952e66d5a64cf88a905e377b3b0ea0
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spelling oai:doaj.org-article:b6952e66d5a64cf88a905e377b3b0ea02021-12-02T15:36:20ZAir-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond10.1038/s41467-019-08513-62041-1723https://doaj.org/article/b6952e66d5a64cf88a905e377b3b0ea02019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08513-6https://doaj.org/toc/2041-1723Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron.Fupin LiuGeorgios VelkosDenis S. KrylovLukas SpreeMichal ZaliberaRajyavardhan RayNataliya A. SamoylovaChia-Hsiang ChenMarco RosenkranzSandra SchiemenzFrank ZiegsKonstantin NenkovAram KostanyanThomas GreberAnja U. B. WolterManuel RichterBernd BüchnerStanislav M. AvdoshenkoAlexey A. PopovNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Fupin Liu
Georgios Velkos
Denis S. Krylov
Lukas Spree
Michal Zalibera
Rajyavardhan Ray
Nataliya A. Samoylova
Chia-Hsiang Chen
Marco Rosenkranz
Sandra Schiemenz
Frank Ziegs
Konstantin Nenkov
Aram Kostanyan
Thomas Greber
Anja U. B. Wolter
Manuel Richter
Bernd Büchner
Stanislav M. Avdoshenko
Alexey A. Popov
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
description Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron.
format article
author Fupin Liu
Georgios Velkos
Denis S. Krylov
Lukas Spree
Michal Zalibera
Rajyavardhan Ray
Nataliya A. Samoylova
Chia-Hsiang Chen
Marco Rosenkranz
Sandra Schiemenz
Frank Ziegs
Konstantin Nenkov
Aram Kostanyan
Thomas Greber
Anja U. B. Wolter
Manuel Richter
Bernd Büchner
Stanislav M. Avdoshenko
Alexey A. Popov
author_facet Fupin Liu
Georgios Velkos
Denis S. Krylov
Lukas Spree
Michal Zalibera
Rajyavardhan Ray
Nataliya A. Samoylova
Chia-Hsiang Chen
Marco Rosenkranz
Sandra Schiemenz
Frank Ziegs
Konstantin Nenkov
Aram Kostanyan
Thomas Greber
Anja U. B. Wolter
Manuel Richter
Bernd Büchner
Stanislav M. Avdoshenko
Alexey A. Popov
author_sort Fupin Liu
title Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
title_short Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
title_full Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
title_fullStr Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
title_full_unstemmed Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
title_sort air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/b6952e66d5a64cf88a905e377b3b0ea0
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