Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is play...
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Nature Portfolio
2019
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oai:doaj.org-article:b6952e66d5a64cf88a905e377b3b0ea02021-12-02T15:36:20ZAir-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond10.1038/s41467-019-08513-62041-1723https://doaj.org/article/b6952e66d5a64cf88a905e377b3b0ea02019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08513-6https://doaj.org/toc/2041-1723Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron.Fupin LiuGeorgios VelkosDenis S. KrylovLukas SpreeMichal ZaliberaRajyavardhan RayNataliya A. SamoylovaChia-Hsiang ChenMarco RosenkranzSandra SchiemenzFrank ZiegsKonstantin NenkovAram KostanyanThomas GreberAnja U. B. WolterManuel RichterBernd BüchnerStanislav M. AvdoshenkoAlexey A. PopovNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019) |
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Science Q Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
description |
Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron. |
format |
article |
author |
Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov |
author_facet |
Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov |
author_sort |
Fupin Liu |
title |
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
title_short |
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
title_full |
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
title_fullStr |
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
title_full_unstemmed |
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
title_sort |
air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/b6952e66d5a64cf88a905e377b3b0ea0 |
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