Plasmonic tunnel junctions for single-molecule redox chemistry

Plasmons in sub-nm cavities can enable chemical processes within plasmonic hotspots. Here the authors use surface-enhanced Raman spectroscopy to track hot-electron-induced chemical reduction processes in aromatic molecules, thus enabling observation of redox processes at the single-molecule level.

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Autores principales:	Bart de Nijs, Felix Benz, Steven J. Barrow, Daniel O. Sigle, Rohit Chikkaraddy, Aniello Palma, Cloudy Carnegie, Marlous Kamp, Ravishankar Sundararaman, Prineha Narang, Oren A. Scherman, Jeremy J. Baumberg
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/b69eb21bd1db4dc790dee85a13e73283
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spelling	oai:doaj.org-article:b69eb21bd1db4dc790dee85a13e732832021-12-02T14:42:09ZPlasmonic tunnel junctions for single-molecule redox chemistry10.1038/s41467-017-00819-72041-1723https://doaj.org/article/b69eb21bd1db4dc790dee85a13e732832017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00819-7https://doaj.org/toc/2041-1723Plasmons in sub-nm cavities can enable chemical processes within plasmonic hotspots. Here the authors use surface-enhanced Raman spectroscopy to track hot-electron-induced chemical reduction processes in aromatic molecules, thus enabling observation of redox processes at the single-molecule level.Bart de NijsFelix BenzSteven J. BarrowDaniel O. SigleRohit ChikkaraddyAniello PalmaCloudy CarnegieMarlous KampRavishankar SundararamanPrineha NarangOren A. SchermanJeremy J. BaumbergNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bart de Nijs Felix Benz Steven J. Barrow Daniel O. Sigle Rohit Chikkaraddy Aniello Palma Cloudy Carnegie Marlous Kamp Ravishankar Sundararaman Prineha Narang Oren A. Scherman Jeremy J. Baumberg Plasmonic tunnel junctions for single-molecule redox chemistry
description	Plasmons in sub-nm cavities can enable chemical processes within plasmonic hotspots. Here the authors use surface-enhanced Raman spectroscopy to track hot-electron-induced chemical reduction processes in aromatic molecules, thus enabling observation of redox processes at the single-molecule level.
format	article
author	Bart de Nijs Felix Benz Steven J. Barrow Daniel O. Sigle Rohit Chikkaraddy Aniello Palma Cloudy Carnegie Marlous Kamp Ravishankar Sundararaman Prineha Narang Oren A. Scherman Jeremy J. Baumberg
author_facet	Bart de Nijs Felix Benz Steven J. Barrow Daniel O. Sigle Rohit Chikkaraddy Aniello Palma Cloudy Carnegie Marlous Kamp Ravishankar Sundararaman Prineha Narang Oren A. Scherman Jeremy J. Baumberg
author_sort	Bart de Nijs
title	Plasmonic tunnel junctions for single-molecule redox chemistry
title_short	Plasmonic tunnel junctions for single-molecule redox chemistry
title_full	Plasmonic tunnel junctions for single-molecule redox chemistry
title_fullStr	Plasmonic tunnel junctions for single-molecule redox chemistry
title_full_unstemmed	Plasmonic tunnel junctions for single-molecule redox chemistry
title_sort	plasmonic tunnel junctions for single-molecule redox chemistry
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/b69eb21bd1db4dc790dee85a13e73283
work_keys_str_mv	AT bartdenijs plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT felixbenz plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT stevenjbarrow plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT danielosigle plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT rohitchikkaraddy plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT aniellopalma plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT cloudycarnegie plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT marlouskamp plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT ravishankarsundararaman plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT prinehanarang plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT orenascherman plasmonictunneljunctionsforsinglemoleculeredoxchemistry AT jeremyjbaumberg plasmonictunneljunctionsforsinglemoleculeredoxchemistry
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Plasmonic tunnel junctions for single-molecule redox chemistry

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