Plasmonic tunnel junctions for single-molecule redox chemistry

Plasmons in sub-nm cavities can enable chemical processes within plasmonic hotspots. Here the authors use surface-enhanced Raman spectroscopy to track hot-electron-induced chemical reduction processes in aromatic molecules, thus enabling observation of redox processes at the single-molecule level.

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Auteurs principaux: Bart de Nijs, Felix Benz, Steven J. Barrow, Daniel O. Sigle, Rohit Chikkaraddy, Aniello Palma, Cloudy Carnegie, Marlous Kamp, Ravishankar Sundararaman, Prineha Narang, Oren A. Scherman, Jeremy J. Baumberg
Format: article
Langue:EN
Publié: Nature Portfolio 2017
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Accès en ligne:https://doaj.org/article/b69eb21bd1db4dc790dee85a13e73283
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