Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation

Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure form when optically active starting materials ar...

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Autores principales:	Xin Huang, Shangze Wu, Wangteng Wu, Pengbin Li, Chunling Fu, Shengming Ma
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/b6c82ba35c4b4f7f9e58b8e16e735bde
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spelling	oai:doaj.org-article:b6c82ba35c4b4f7f9e58b8e16e735bde2021-12-02T17:31:48ZPalladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation10.1038/ncomms123822041-1723https://doaj.org/article/b6c82ba35c4b4f7f9e58b8e16e735bde2016-08-01T00:00:00Zhttps://doi.org/10.1038/ncomms12382https://doaj.org/toc/2041-1723Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure form when optically active starting materials are employed.Xin HuangShangze WuWangteng WuPengbin LiChunling FuShengming MaNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xin Huang Shangze Wu Wangteng Wu Pengbin Li Chunling Fu Shengming Ma Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
description	Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure form when optically active starting materials are employed.
format	article
author	Xin Huang Shangze Wu Wangteng Wu Pengbin Li Chunling Fu Shengming Ma
author_facet	Xin Huang Shangze Wu Wangteng Wu Pengbin Li Chunling Fu Shengming Ma
author_sort	Xin Huang
title	Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
title_short	Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
title_full	Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
title_fullStr	Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
title_full_unstemmed	Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
title_sort	palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/b6c82ba35c4b4f7f9e58b8e16e735bde
work_keys_str_mv	AT xinhuang palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation AT shangzewu palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation AT wangtengwu palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation AT pengbinli palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation AT chunlingfu palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation AT shengmingma palladiumcatalysedformationofvicinalallcarbonquaternarycentresviapropargylation
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Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation

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