Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation

Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure form when optically active starting materials ar...

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Autores principales: Xin Huang, Shangze Wu, Wangteng Wu, Pengbin Li, Chunling Fu, Shengming Ma
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/b6c82ba35c4b4f7f9e58b8e16e735bde
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