An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions

Abstract The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of benzonitriles and diarylethers of aryl halides under optimal conditions. The MOF catalyst was built based on magnetic nanoparticles and UiO-66-NH2 which further modified with 2,4,6-tr...

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Autores principales:	Firouz Matloubi Moghaddam, Atefeh Jarahiyan, Mahdi Heidarian Haris, Ali Pourjavadi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/b6f400265cf7459a9e58238e5d1c915a
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spelling	oai:doaj.org-article:b6f400265cf7459a9e58238e5d1c915a2021-12-02T18:24:54ZAn advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions10.1038/s41598-021-90478-y2045-2322https://doaj.org/article/b6f400265cf7459a9e58238e5d1c915a2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-90478-yhttps://doaj.org/toc/2045-2322Abstract The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of benzonitriles and diarylethers of aryl halides under optimal conditions. The MOF catalyst was built based on magnetic nanoparticles and UiO-66-NH2 which further modified with 2,4,6-trichloro-1,3,5-triazine and 5-phenyl tetrazole at the same time and the catalyst structure was confirmed by various techniques. This new modification has been applied to increase anchoring palladium into the support. Furthermore, the products’ yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing palladium. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs.Firouz Matloubi MoghaddamAtefeh JarahiyanMahdi Heidarian HarisAli PourjavadiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-17 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Firouz Matloubi Moghaddam Atefeh Jarahiyan Mahdi Heidarian Haris Ali Pourjavadi An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
description	Abstract The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of benzonitriles and diarylethers of aryl halides under optimal conditions. The MOF catalyst was built based on magnetic nanoparticles and UiO-66-NH2 which further modified with 2,4,6-trichloro-1,3,5-triazine and 5-phenyl tetrazole at the same time and the catalyst structure was confirmed by various techniques. This new modification has been applied to increase anchoring palladium into the support. Furthermore, the products’ yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing palladium. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs.
format	article
author	Firouz Matloubi Moghaddam Atefeh Jarahiyan Mahdi Heidarian Haris Ali Pourjavadi
author_facet	Firouz Matloubi Moghaddam Atefeh Jarahiyan Mahdi Heidarian Haris Ali Pourjavadi
author_sort	Firouz Matloubi Moghaddam
title	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
title_short	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
title_full	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
title_fullStr	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
title_full_unstemmed	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions
title_sort	advancement in the synthesis of nano pd@magnetic amine-functionalized uio-66-nh2 catalyst for cyanation and o-arylation reactions
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/b6f400265cf7459a9e58238e5d1c915a
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An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions

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