Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes

The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of...

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Autores principales: Yali Zhou, Xingjun Xu, Hongwei Sun, Guanyu Tao, Xiao-Yong Chang, Xiangyou Xing, Bo Chen, Chen Xu
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/b7558009dee04f8caca8209b803af4dc
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spelling oai:doaj.org-article:b7558009dee04f8caca8209b803af4dc2021-12-02T13:26:41ZDevelopment of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes10.1038/s41467-021-22287-w2041-1723https://doaj.org/article/b7558009dee04f8caca8209b803af4dc2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22287-whttps://doaj.org/toc/2041-1723The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.Yali ZhouXingjun XuHongwei SunGuanyu TaoXiao-Yong ChangXiangyou XingBo ChenChen XuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yali Zhou
Xingjun Xu
Hongwei Sun
Guanyu Tao
Xiao-Yong Chang
Xiangyou Xing
Bo Chen
Chen Xu
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
description The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.
format article
author Yali Zhou
Xingjun Xu
Hongwei Sun
Guanyu Tao
Xiao-Yong Chang
Xiangyou Xing
Bo Chen
Chen Xu
author_facet Yali Zhou
Xingjun Xu
Hongwei Sun
Guanyu Tao
Xiao-Yong Chang
Xiangyou Xing
Bo Chen
Chen Xu
author_sort Yali Zhou
title Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_short Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_full Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_fullStr Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_full_unstemmed Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_sort development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/b7558009dee04f8caca8209b803af4dc
work_keys_str_mv AT yalizhou developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT xingjunxu developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT hongweisun developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT guanyutao developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT xiaoyongchang developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT xiangyouxing developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT bochen developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
AT chenxu developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes
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