Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of...
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Nature Portfolio
2021
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oai:doaj.org-article:b7558009dee04f8caca8209b803af4dc2021-12-02T13:26:41ZDevelopment of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes10.1038/s41467-021-22287-w2041-1723https://doaj.org/article/b7558009dee04f8caca8209b803af4dc2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22287-whttps://doaj.org/toc/2041-1723The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.Yali ZhouXingjun XuHongwei SunGuanyu TaoXiao-Yong ChangXiangyou XingBo ChenChen XuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021) |
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Science Q Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
description |
The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions. |
format |
article |
author |
Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu |
author_facet |
Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu |
author_sort |
Yali Zhou |
title |
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
title_short |
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
title_full |
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
title_fullStr |
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
title_full_unstemmed |
Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
title_sort |
development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/b7558009dee04f8caca8209b803af4dc |
work_keys_str_mv |
AT yalizhou developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT xingjunxu developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT hongweisun developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT guanyutao developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT xiaoyongchang developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT xiangyouxing developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT bochen developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes AT chenxu developmentofhighlyefficientplatinumcatalystsforhydroalkoxylationandhydroaminationofunactivatedalkenes |
_version_ |
1718393054388289536 |