Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate

Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-...

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Autor principal:	Melnic, Elena
Formato:	article
Lenguaje:	EN
Publicado:	D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2016
Materias:	Physics QC1-999 Electronics TK7800-8360
Acceso en línea:	https://doaj.org/article/b7c0a86da8694602835ad9310929de35
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spelling	oai:doaj.org-article:b7c0a86da8694602835ad9310929de352021-11-21T11:57:26ZStacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate548+532537-63651810-648Xhttps://doaj.org/article/b7c0a86da8694602835ad9310929de352016-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2016/article/50387https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The supramolecular structures of these novel complexes and related complexes found in the Cambridge Structural Database (CSD), which contain a planar [Cu(acac)(AA)] fragment, where AA denotes phen or 2,2´-bipyridine (bipy)/4,4´-dimethyl-2,2´-dipyridine (Me2bipy), have been analyzed from in terms of stacking interactions in these systems. Melnic, ElenaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 15, Iss 3-4, Pp 193-207 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physics QC1-999 Electronics TK7800-8360
spellingShingle	Physics QC1-999 Electronics TK7800-8360 Melnic, Elena Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
description	Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The supramolecular structures of these novel complexes and related complexes found in the Cambridge Structural Database (CSD), which contain a planar [Cu(acac)(AA)] fragment, where AA denotes phen or 2,2´-bipyridine (bipy)/4,4´-dimethyl-2,2´-dipyridine (Me2bipy), have been analyzed from in terms of stacking interactions in these systems.
format	article
author	Melnic, Elena
author_facet	Melnic, Elena
author_sort	Melnic, Elena
title	Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
title_short	Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
title_full	Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
title_fullStr	Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
title_full_unstemmed	Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
title_sort	stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate
publisher	D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate	2016
url	https://doaj.org/article/b7c0a86da8694602835ad9310929de35
work_keys_str_mv	AT melnicelena stackinginteractionsinthecrystalstructuresofmixedligandsquarepyramidalcopperiicomplexeswitharomatic110phenanthrolineor22bipyridineligandsandacetylacetonate
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Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate

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