Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers

Spin selectivity for electron transport through peptide monolayers depends on the dipole moment of the system. Here, the authors show that self-assembled monolayers of peptides with α-helix structures transform to more linear structures upon cooling, inducing a flip in the direction of dipole moment...

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Autores principales: Meital Eckshtain-Levi, Eyal Capua, Sivan Refaely-Abramson, Soumyajit Sarkar, Yulian Gavrilov, Shinto P. Mathew, Yossi Paltiel, Yaakov Levy, Leeor Kronik, Ron Naaman
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Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/b7f37c177fdc40e2b8a397d4c797c58f
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spelling oai:doaj.org-article:b7f37c177fdc40e2b8a397d4c797c58f2021-12-02T14:40:16ZCold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers10.1038/ncomms107442041-1723https://doaj.org/article/b7f37c177fdc40e2b8a397d4c797c58f2016-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms10744https://doaj.org/toc/2041-1723Spin selectivity for electron transport through peptide monolayers depends on the dipole moment of the system. Here, the authors show that self-assembled monolayers of peptides with α-helix structures transform to more linear structures upon cooling, inducing a flip in the direction of dipole moment and a change in preferred spin for electron transport.Meital Eckshtain-LeviEyal CapuaSivan Refaely-AbramsonSoumyajit SarkarYulian GavrilovShinto P. MathewYossi PaltielYaakov LevyLeeor KronikRon NaamanNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-9 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Meital Eckshtain-Levi
Eyal Capua
Sivan Refaely-Abramson
Soumyajit Sarkar
Yulian Gavrilov
Shinto P. Mathew
Yossi Paltiel
Yaakov Levy
Leeor Kronik
Ron Naaman
Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
description Spin selectivity for electron transport through peptide monolayers depends on the dipole moment of the system. Here, the authors show that self-assembled monolayers of peptides with α-helix structures transform to more linear structures upon cooling, inducing a flip in the direction of dipole moment and a change in preferred spin for electron transport.
format article
author Meital Eckshtain-Levi
Eyal Capua
Sivan Refaely-Abramson
Soumyajit Sarkar
Yulian Gavrilov
Shinto P. Mathew
Yossi Paltiel
Yaakov Levy
Leeor Kronik
Ron Naaman
author_facet Meital Eckshtain-Levi
Eyal Capua
Sivan Refaely-Abramson
Soumyajit Sarkar
Yulian Gavrilov
Shinto P. Mathew
Yossi Paltiel
Yaakov Levy
Leeor Kronik
Ron Naaman
author_sort Meital Eckshtain-Levi
title Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
title_short Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
title_full Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
title_fullStr Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
title_full_unstemmed Cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
title_sort cold denaturation induces inversion of dipole and spin transfer in chiral peptide monolayers
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/b7f37c177fdc40e2b8a397d4c797c58f
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