Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate

The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+}n, held...

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Autores principales:	Rafael A. Adrian, Sara J. Ibarra, Hadi D. Arman
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	crystal structure silver atom isonicotinamide trifluoromethanesulfonate ions acetonitrile polymeric structure Crystallography QD901-999
Acceso en línea:	https://doaj.org/article/b816d4166854450f8c2d0e1a9500a8c3
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spelling	oai:doaj.org-article:b816d4166854450f8c2d0e1a9500a8c32021-11-12T12:26:16ZBis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate2414-314610.1107/S2414314621010737https://doaj.org/article/b816d4166854450f8c2d0e1a9500a8c32021-10-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2414314621010737https://doaj.org/toc/2414-3146The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+}n, held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating acetonitrile molecules that interact the silver metal center via regium bonds.Rafael A. AdrianSara J. IbarraHadi D. ArmanInternational Union of Crystallographyarticlecrystal structuresilver atomisonicotinamidetrifluoromethanesulfonate ionsacetonitrilepolymeric structureCrystallographyQD901-999ENIUCrData, Vol 6, Iss 10, p x211073 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure silver atom isonicotinamide trifluoromethanesulfonate ions acetonitrile polymeric structure Crystallography QD901-999
spellingShingle	crystal structure silver atom isonicotinamide trifluoromethanesulfonate ions acetonitrile polymeric structure Crystallography QD901-999 Rafael A. Adrian Sara J. Ibarra Hadi D. Arman Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
description	The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+}n, held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating acetonitrile molecules that interact the silver metal center via regium bonds.
format	article
author	Rafael A. Adrian Sara J. Ibarra Hadi D. Arman
author_facet	Rafael A. Adrian Sara J. Ibarra Hadi D. Arman
author_sort	Rafael A. Adrian
title	Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
title_short	Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
title_full	Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
title_fullStr	Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
title_full_unstemmed	Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
title_sort	bis(isonicotinamide-κn)silver(i) trifluoromethanesulfonate acetonitrile disolvate
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/b816d4166854450f8c2d0e1a9500a8c3
work_keys_str_mv	AT rafaelaadrian bisisonicotinamideknsilveritrifluoromethanesulfonateacetonitriledisolvate AT sarajibarra bisisonicotinamideknsilveritrifluoromethanesulfonateacetonitriledisolvate AT hadidarman bisisonicotinamideknsilveritrifluoromethanesulfonateacetonitriledisolvate
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Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate

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