Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne

Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.

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Detalles Bibliográficos
Autores principales: Yiming Niu, Xing Huang, Yongzhao Wang, Ming Xu, Junnan Chen, Shuliang Xu, Marc-Georg Willinger, Wei Zhang, Min Wei, Bingsen Zhang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c
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Sumario:Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.