Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne

Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.

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Autores principales: Yiming Niu, Xing Huang, Yongzhao Wang, Ming Xu, Junnan Chen, Shuliang Xu, Marc-Georg Willinger, Wei Zhang, Min Wei, Bingsen Zhang
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Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c
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spelling oai:doaj.org-article:b82ce62357d04002a59c038c2ef5908c2021-12-02T16:32:14ZManipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne10.1038/s41467-020-17188-32041-1723https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c2020-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17188-3https://doaj.org/toc/2041-1723Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.Yiming NiuXing HuangYongzhao WangMing XuJunnan ChenShuliang XuMarc-Georg WillingerWei ZhangMin WeiBingsen ZhangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yiming Niu
Xing Huang
Yongzhao Wang
Ming Xu
Junnan Chen
Shuliang Xu
Marc-Georg Willinger
Wei Zhang
Min Wei
Bingsen Zhang
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
description Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.
format article
author Yiming Niu
Xing Huang
Yongzhao Wang
Ming Xu
Junnan Chen
Shuliang Xu
Marc-Georg Willinger
Wei Zhang
Min Wei
Bingsen Zhang
author_facet Yiming Niu
Xing Huang
Yongzhao Wang
Ming Xu
Junnan Chen
Shuliang Xu
Marc-Georg Willinger
Wei Zhang
Min Wei
Bingsen Zhang
author_sort Yiming Niu
title Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
title_short Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
title_full Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
title_fullStr Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
title_full_unstemmed Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
title_sort manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c
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