Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne
Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.
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Nature Portfolio
2020
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oai:doaj.org-article:b82ce62357d04002a59c038c2ef5908c2021-12-02T16:32:14ZManipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne10.1038/s41467-020-17188-32041-1723https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c2020-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17188-3https://doaj.org/toc/2041-1723Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction.Yiming NiuXing HuangYongzhao WangMing XuJunnan ChenShuliang XuMarc-Georg WillingerWei ZhangMin WeiBingsen ZhangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020) |
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Science Q Yiming Niu Xing Huang Yongzhao Wang Ming Xu Junnan Chen Shuliang Xu Marc-Georg Willinger Wei Zhang Min Wei Bingsen Zhang Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
description |
Design and synthesis of non-noble metal catalysts is crucial for highly-efficient hydrogenation. Here, the interstitial sites in nickel are manipulated with zinc and filled by dissociated carbon atoms, which drastically improve the selectivity/stability in acetylene hydrogenation reaction. |
format |
article |
author |
Yiming Niu Xing Huang Yongzhao Wang Ming Xu Junnan Chen Shuliang Xu Marc-Georg Willinger Wei Zhang Min Wei Bingsen Zhang |
author_facet |
Yiming Niu Xing Huang Yongzhao Wang Ming Xu Junnan Chen Shuliang Xu Marc-Georg Willinger Wei Zhang Min Wei Bingsen Zhang |
author_sort |
Yiming Niu |
title |
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
title_short |
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
title_full |
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
title_fullStr |
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
title_full_unstemmed |
Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
title_sort |
manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/b82ce62357d04002a59c038c2ef5908c |
work_keys_str_mv |
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