Multi-functional 2D hybrid aerogels for gas absorption applications

Abstract Aerogels have attracted significant attention recently due to their ultra-light weight porous structure, mechanical robustness, high electrical conductivity, facile scalability and their use as gas and oil absorbers. Herein, we examine the multi-functional properties of hybrid aerogels cons...

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Autores principales: Charalampos Androulidakis, Maria Kotsidi, George Gorgolis, Christos Pavlou, Labrini Sygellou, George Paterakis, Nick Koutroumanis, Costas Galiotis
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Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/b8fbc39a4d184cfd812a5dd933123907
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spelling oai:doaj.org-article:b8fbc39a4d184cfd812a5dd9331239072021-12-02T14:33:57ZMulti-functional 2D hybrid aerogels for gas absorption applications10.1038/s41598-021-92957-82045-2322https://doaj.org/article/b8fbc39a4d184cfd812a5dd9331239072021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-92957-8https://doaj.org/toc/2045-2322Abstract Aerogels have attracted significant attention recently due to their ultra-light weight porous structure, mechanical robustness, high electrical conductivity, facile scalability and their use as gas and oil absorbers. Herein, we examine the multi-functional properties of hybrid aerogels consisting of reduced graphene oxide (rGO) integrated with hexagonal boron nitride (hBN) platelets. Using a freeze-drying approach, hybrid aerogels are fabricated by simple mixing with various volume fractions of hBN and rGO up to 0.5/0.5 ratio. The fabrication method is simple, cost effective, scalable and can be extended to other 2D materials combinations. The hybrid rGO/hBN aerogels (HAs) are mechanically robust and highly compressible with mechanical properties similar to those of the pure rGO aerogel. We show that the presence of hBN in the HAs enhances the gas absorption capacities of formaldehyde and water vapour up to ~ 7 and > 8 times, respectively, as compared to pure rGO aerogel. Moreover, the samples show good recoverability, making them highly efficient materials for gas absorption applications and for the protection of artefacts such as paintings in storage facilities. Finally, even in the presence of large quantity of insulating hBN, the HAs are electrically conductive, extending the potential application spectrum of the proposed hybrids to the field of electro-thermal actuators. The work proposed here paves the way for the design and production of novel 2D materials combinations with tailored multi-functionalities suited for a large variety of modern applications.Charalampos AndroulidakisMaria KotsidiGeorge GorgolisChristos PavlouLabrini SygellouGeorge PaterakisNick KoutroumanisCostas GaliotisNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-12 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Charalampos Androulidakis
Maria Kotsidi
George Gorgolis
Christos Pavlou
Labrini Sygellou
George Paterakis
Nick Koutroumanis
Costas Galiotis
Multi-functional 2D hybrid aerogels for gas absorption applications
description Abstract Aerogels have attracted significant attention recently due to their ultra-light weight porous structure, mechanical robustness, high electrical conductivity, facile scalability and their use as gas and oil absorbers. Herein, we examine the multi-functional properties of hybrid aerogels consisting of reduced graphene oxide (rGO) integrated with hexagonal boron nitride (hBN) platelets. Using a freeze-drying approach, hybrid aerogels are fabricated by simple mixing with various volume fractions of hBN and rGO up to 0.5/0.5 ratio. The fabrication method is simple, cost effective, scalable and can be extended to other 2D materials combinations. The hybrid rGO/hBN aerogels (HAs) are mechanically robust and highly compressible with mechanical properties similar to those of the pure rGO aerogel. We show that the presence of hBN in the HAs enhances the gas absorption capacities of formaldehyde and water vapour up to ~ 7 and > 8 times, respectively, as compared to pure rGO aerogel. Moreover, the samples show good recoverability, making them highly efficient materials for gas absorption applications and for the protection of artefacts such as paintings in storage facilities. Finally, even in the presence of large quantity of insulating hBN, the HAs are electrically conductive, extending the potential application spectrum of the proposed hybrids to the field of electro-thermal actuators. The work proposed here paves the way for the design and production of novel 2D materials combinations with tailored multi-functionalities suited for a large variety of modern applications.
format article
author Charalampos Androulidakis
Maria Kotsidi
George Gorgolis
Christos Pavlou
Labrini Sygellou
George Paterakis
Nick Koutroumanis
Costas Galiotis
author_facet Charalampos Androulidakis
Maria Kotsidi
George Gorgolis
Christos Pavlou
Labrini Sygellou
George Paterakis
Nick Koutroumanis
Costas Galiotis
author_sort Charalampos Androulidakis
title Multi-functional 2D hybrid aerogels for gas absorption applications
title_short Multi-functional 2D hybrid aerogels for gas absorption applications
title_full Multi-functional 2D hybrid aerogels for gas absorption applications
title_fullStr Multi-functional 2D hybrid aerogels for gas absorption applications
title_full_unstemmed Multi-functional 2D hybrid aerogels for gas absorption applications
title_sort multi-functional 2d hybrid aerogels for gas absorption applications
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/b8fbc39a4d184cfd812a5dd933123907
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