Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process

A novel technology for the simultaneous removal of NOx (= NO + NO2) and SOx (= SO2 + SO3) in the flue gas of a glass manufacturing system is described using a plasma-chemical hybrid process (PCHP). The exhaust gas is produced by combustion of liquefied natural gas and contains both NOx (189 - 335 pp...

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Autores principales: Hashira YAMAMOTO, Tomoyuki KUROKI, Hidekatsu FUJISHIMA, Masaaki OKUBO
Formato: article
Lenguaje:EN
Publicado: The Japan Society of Mechanical Engineers 2016
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Acceso en línea:https://doaj.org/article/b93bf8a5b2fa4474a884a9f4498726b9
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spelling oai:doaj.org-article:b93bf8a5b2fa4474a884a9f4498726b92021-11-26T06:35:13ZPilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process2187-974510.1299/mej.15-00549https://doaj.org/article/b93bf8a5b2fa4474a884a9f4498726b92016-02-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/mej/3/1/3_15-00549/_pdf/-char/enhttps://doaj.org/toc/2187-9745A novel technology for the simultaneous removal of NOx (= NO + NO2) and SOx (= SO2 + SO3) in the flue gas of a glass manufacturing system is described using a plasma-chemical hybrid process (PCHP). The exhaust gas is produced by combustion of liquefied natural gas and contains both NOx (189 - 335 ppm) and SOx (109 - 183 ppm). Lowering the flue gas temperature from more than 200 °C to less than 150 °C is required for effective NO oxidation (80% efficiency) to NO2 by ozone gas injection. Therefore, a mixture of ozone and water are sprayed by compressed air from the three-fluid spray nozzle into the exhaust duct. The ozone gas is prepared using an electrical discharge-induced nonthermal plasma apparatus. In addition, almost all of the SO2 is absorbed by a NaOH absorbent resulting in the generation of Na2SO3. Furthermore, reduction of the water-soluble NO2 by Na2SO3 to N2 affords Na2SO4, which can be reused as glass material. The highest removal efficiency of 39% for NOx is obtained when the NOx concentration is reduced from 315 ppm to 193 ppm (O3/NO = 0.32). This simultaneous de-SOx and de-NOx technology by PCHP is highly effective and promising for exhaust gas treatment for a glass manufacturing system.Hashira YAMAMOTOTomoyuki KUROKIHidekatsu FUJISHIMAMasaaki OKUBOThe Japan Society of Mechanical Engineersarticleglass manufacturing systemnoxdenitrationsoxdesulfurizationozoneplasma chemistrynonthermal plasma na2so3Mechanical engineering and machineryTJ1-1570ENMechanical Engineering Journal, Vol 3, Iss 1, Pp 15-00549-15-00549 (2016)
institution DOAJ
collection DOAJ
language EN
topic glass manufacturing system
nox
denitration
sox
desulfurization
ozone
plasma chemistry
nonthermal plasma
na2so3
Mechanical engineering and machinery
TJ1-1570
spellingShingle glass manufacturing system
nox
denitration
sox
desulfurization
ozone
plasma chemistry
nonthermal plasma
na2so3
Mechanical engineering and machinery
TJ1-1570
Hashira YAMAMOTO
Tomoyuki KUROKI
Hidekatsu FUJISHIMA
Masaaki OKUBO
Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
description A novel technology for the simultaneous removal of NOx (= NO + NO2) and SOx (= SO2 + SO3) in the flue gas of a glass manufacturing system is described using a plasma-chemical hybrid process (PCHP). The exhaust gas is produced by combustion of liquefied natural gas and contains both NOx (189 - 335 ppm) and SOx (109 - 183 ppm). Lowering the flue gas temperature from more than 200 °C to less than 150 °C is required for effective NO oxidation (80% efficiency) to NO2 by ozone gas injection. Therefore, a mixture of ozone and water are sprayed by compressed air from the three-fluid spray nozzle into the exhaust duct. The ozone gas is prepared using an electrical discharge-induced nonthermal plasma apparatus. In addition, almost all of the SO2 is absorbed by a NaOH absorbent resulting in the generation of Na2SO3. Furthermore, reduction of the water-soluble NO2 by Na2SO3 to N2 affords Na2SO4, which can be reused as glass material. The highest removal efficiency of 39% for NOx is obtained when the NOx concentration is reduced from 315 ppm to 193 ppm (O3/NO = 0.32). This simultaneous de-SOx and de-NOx technology by PCHP is highly effective and promising for exhaust gas treatment for a glass manufacturing system.
format article
author Hashira YAMAMOTO
Tomoyuki KUROKI
Hidekatsu FUJISHIMA
Masaaki OKUBO
author_facet Hashira YAMAMOTO
Tomoyuki KUROKI
Hidekatsu FUJISHIMA
Masaaki OKUBO
author_sort Hashira YAMAMOTO
title Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
title_short Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
title_full Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
title_fullStr Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
title_full_unstemmed Pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
title_sort pilot-scale exhaust gas treatment for a glass manufacturing system using a plasma combined wet chemical process
publisher The Japan Society of Mechanical Engineers
publishDate 2016
url https://doaj.org/article/b93bf8a5b2fa4474a884a9f4498726b9
work_keys_str_mv AT hashirayamamoto pilotscaleexhaustgastreatmentforaglassmanufacturingsystemusingaplasmacombinedwetchemicalprocess
AT tomoyukikuroki pilotscaleexhaustgastreatmentforaglassmanufacturingsystemusingaplasmacombinedwetchemicalprocess
AT hidekatsufujishima pilotscaleexhaustgastreatmentforaglassmanufacturingsystemusingaplasmacombinedwetchemicalprocess
AT masaakiokubo pilotscaleexhaustgastreatmentforaglassmanufacturingsystemusingaplasmacombinedwetchemicalprocess
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