Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys

The microstructure, phase composition, and mechanical properties of NbTiZr, TaTiZr, Re<sub>0.3</sub>NbTiZr, and Re<sub>0.3</sub>TaTiZr are reported. The alloys were produced by vacuum arc melting and hot isostatically pressed (HIP’d) at 1400 °C for 3 h under 276 MPa hydrostat...

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Autores principales: Oleg N. Senkov, Stéphane Gorsse, Robert Wheeler, Eric J. Payton, Daniel B. Miracle
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:b94a9be136eb4bf7bc1eacf724f79e452021-11-25T18:22:11ZEffect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys10.3390/met111118192075-4701https://doaj.org/article/b94a9be136eb4bf7bc1eacf724f79e452021-11-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1819https://doaj.org/toc/2075-4701The microstructure, phase composition, and mechanical properties of NbTiZr, TaTiZr, Re<sub>0.3</sub>NbTiZr, and Re<sub>0.3</sub>TaTiZr are reported. The alloys were produced by vacuum arc melting and hot isostatically pressed (HIP’d) at 1400 °C for 3 h under 276 MPa hydrostatic pressure of high-purity argon prior to testing. NbTiZr had a single-phase BCC crystal structure, while TaTiZr had a Ti- and Zr-rich BCC matrix phase and Ta-rich nanometer-sized BCC precipitates, at volume fractions of 0.49 and 0.51, respectively. Re<sub>0.3</sub>NbTiZr consisted of a BCC matrix phase and Re-rich precipitates with a FCC crystal structure and the volume fraction of 0.14. The microstructure of Re<sub>0.3</sub>TaTiZr consisted of a Zr-rich BCC matrix phase and coarse, Re and Ta rich, BCC particles, which volume fraction was 0.47. NbTiZr and TaTiZr had a room temperature (RT) yield stress of 920 MPa and 1670 MPa, respectively. While, 10 at.% Re additions increased the RT yield stress to 1220 MPa in Re<sub>0.3</sub>NbTiZr and 1715 MPa in Re<sub>0.3</sub>TaTiZr. Re also considerably improved the RT ductility of TaTiZr, from about 2.5% to 10% of true strain. The positive strengthening effect from the Re additions was retained at high (800–1200 °C) temperatures.Oleg N. SenkovStéphane GorsseRobert WheelerEric J. PaytonDaniel B. MiracleMDPI AGarticlerefractory alloymicrostructurephase compositionCALPHADmechanical propertiesMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1819, p 1819 (2021)
institution DOAJ
collection DOAJ
language EN
topic refractory alloy
microstructure
phase composition
CALPHAD
mechanical properties
Mining engineering. Metallurgy
TN1-997
spellingShingle refractory alloy
microstructure
phase composition
CALPHAD
mechanical properties
Mining engineering. Metallurgy
TN1-997
Oleg N. Senkov
Stéphane Gorsse
Robert Wheeler
Eric J. Payton
Daniel B. Miracle
Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
description The microstructure, phase composition, and mechanical properties of NbTiZr, TaTiZr, Re<sub>0.3</sub>NbTiZr, and Re<sub>0.3</sub>TaTiZr are reported. The alloys were produced by vacuum arc melting and hot isostatically pressed (HIP’d) at 1400 °C for 3 h under 276 MPa hydrostatic pressure of high-purity argon prior to testing. NbTiZr had a single-phase BCC crystal structure, while TaTiZr had a Ti- and Zr-rich BCC matrix phase and Ta-rich nanometer-sized BCC precipitates, at volume fractions of 0.49 and 0.51, respectively. Re<sub>0.3</sub>NbTiZr consisted of a BCC matrix phase and Re-rich precipitates with a FCC crystal structure and the volume fraction of 0.14. The microstructure of Re<sub>0.3</sub>TaTiZr consisted of a Zr-rich BCC matrix phase and coarse, Re and Ta rich, BCC particles, which volume fraction was 0.47. NbTiZr and TaTiZr had a room temperature (RT) yield stress of 920 MPa and 1670 MPa, respectively. While, 10 at.% Re additions increased the RT yield stress to 1220 MPa in Re<sub>0.3</sub>NbTiZr and 1715 MPa in Re<sub>0.3</sub>TaTiZr. Re also considerably improved the RT ductility of TaTiZr, from about 2.5% to 10% of true strain. The positive strengthening effect from the Re additions was retained at high (800–1200 °C) temperatures.
format article
author Oleg N. Senkov
Stéphane Gorsse
Robert Wheeler
Eric J. Payton
Daniel B. Miracle
author_facet Oleg N. Senkov
Stéphane Gorsse
Robert Wheeler
Eric J. Payton
Daniel B. Miracle
author_sort Oleg N. Senkov
title Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
title_short Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
title_full Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
title_fullStr Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
title_full_unstemmed Effect of Re on the Microstructure and Mechanical Properties of NbTiZr and TaTiZr Equiatomic Alloys
title_sort effect of re on the microstructure and mechanical properties of nbtizr and tatizr equiatomic alloys
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/b94a9be136eb4bf7bc1eacf724f79e45
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