Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol

Molecular interactions with both oxides and metals are essential for heterogenous catalysis, leading to remarkable impacts on activity. Here the authors show that a direct link between Cu and ZrO2 in a metal organic framework is required to hydrogenate CO2 to methanol.

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Autores principales:	Yifeng Zhu, Jian Zheng, Jingyun Ye, Yanran Cui, Katherine Koh, Libor Kovarik, Donald M. Camaioni, John L. Fulton, Donald G. Truhlar, Matthew Neurock, Christopher J. Cramer, Oliver Y. Gutiérrez, Johannes A. Lercher
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/b9cc9b6c73f347d99c9579e5b1e6e42f
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spelling	oai:doaj.org-article:b9cc9b6c73f347d99c9579e5b1e6e42f2021-12-02T16:56:31ZCopper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol10.1038/s41467-020-19438-w2041-1723https://doaj.org/article/b9cc9b6c73f347d99c9579e5b1e6e42f2020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19438-whttps://doaj.org/toc/2041-1723Molecular interactions with both oxides and metals are essential for heterogenous catalysis, leading to remarkable impacts on activity. Here the authors show that a direct link between Cu and ZrO2 in a metal organic framework is required to hydrogenate CO2 to methanol.Yifeng ZhuJian ZhengJingyun YeYanran CuiKatherine KohLibor KovarikDonald M. CamaioniJohn L. FultonDonald G. TruhlarMatthew NeurockChristopher J. CramerOliver Y. GutiérrezJohannes A. LercherNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yifeng Zhu Jian Zheng Jingyun Ye Yanran Cui Katherine Koh Libor Kovarik Donald M. Camaioni John L. Fulton Donald G. Truhlar Matthew Neurock Christopher J. Cramer Oliver Y. Gutiérrez Johannes A. Lercher Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
description	Molecular interactions with both oxides and metals are essential for heterogenous catalysis, leading to remarkable impacts on activity. Here the authors show that a direct link between Cu and ZrO2 in a metal organic framework is required to hydrogenate CO2 to methanol.
format	article
author	Yifeng Zhu Jian Zheng Jingyun Ye Yanran Cui Katherine Koh Libor Kovarik Donald M. Camaioni John L. Fulton Donald G. Truhlar Matthew Neurock Christopher J. Cramer Oliver Y. Gutiérrez Johannes A. Lercher
author_facet	Yifeng Zhu Jian Zheng Jingyun Ye Yanran Cui Katherine Koh Libor Kovarik Donald M. Camaioni John L. Fulton Donald G. Truhlar Matthew Neurock Christopher J. Cramer Oliver Y. Gutiérrez Johannes A. Lercher
author_sort	Yifeng Zhu
title	Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
title_short	Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
title_full	Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
title_fullStr	Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
title_full_unstemmed	Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
title_sort	copper-zirconia interfaces in uio-66 enable selective catalytic hydrogenation of co2 to methanol
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/b9cc9b6c73f347d99c9579e5b1e6e42f
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Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol

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