Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes

Methylene blue degradation carried out using cadmium sulfide (CdS) photoanode in photofuel cell (PFC) had been done. CdS synthesized by chemical bath deposition (CBD) on the FTO substrate was used as anode and platinum as a cathode in photoelectrochemical studies. Characterization of CdS thin film w...

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Autores principales: Gunawan Gunawan, Abdul Haris, Didik Setiyo Widodo, Linda Suyati, Wilman Septina
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Lenguaje:EN
Publicado: Department of Chemistry, Universitas Gadjah Mada 2020
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spelling oai:doaj.org-article:b9efcc85313745faaaff479481ae18f42021-12-02T14:04:53ZDegradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes1411-94202460-157810.22146/ijc.53131https://doaj.org/article/b9efcc85313745faaaff479481ae18f42020-11-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/53131https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578Methylene blue degradation carried out using cadmium sulfide (CdS) photoanode in photofuel cell (PFC) had been done. CdS synthesized by chemical bath deposition (CBD) on the FTO substrate was used as anode and platinum as a cathode in photoelectrochemical studies. Characterization of CdS thin film was done using EDX, XRD, SEM, Raman, UV-Vis absorption spectrophotometer as well as photocurrent test of the CdS thin film under illumination using potentiostat with the three-electrode system. The EDX result indicated the presence of CdS with an elemental composition of Cd rich. XRD showed the appearance of CdS crystals in cubic and hexagonal formations. SEM image of CdS gave results in the form of crystals of less than 1 mm. Raman spectrum showed the appearance of CdS peaks. The bandgap of CdS was estimated to be 2.38 eV, and the photocurrent test confirmed that the film had a property of n-type semiconductor. Application of CdS thin film as a photoanode in the PFC system using 100 mg/L methylene blue solution showed degradation up to 48% for 2.5 h using a 4 cm2 photoanode, and the maximum potential of 0.8 V was obtained with a photoanode area of 1 cm2.Gunawan GunawanAbdul HarisDidik Setiyo WidodoLinda SuyatiWilman SeptinaDepartment of Chemistry, Universitas Gadjah Madaarticlecadmium sulphidephotoanodephotofuel cellmethylene blueChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 1, Pp 97-107 (2020)
institution DOAJ
collection DOAJ
language EN
topic cadmium sulphide
photoanode
photofuel cell
methylene blue
Chemistry
QD1-999
spellingShingle cadmium sulphide
photoanode
photofuel cell
methylene blue
Chemistry
QD1-999
Gunawan Gunawan
Abdul Haris
Didik Setiyo Widodo
Linda Suyati
Wilman Septina
Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
description Methylene blue degradation carried out using cadmium sulfide (CdS) photoanode in photofuel cell (PFC) had been done. CdS synthesized by chemical bath deposition (CBD) on the FTO substrate was used as anode and platinum as a cathode in photoelectrochemical studies. Characterization of CdS thin film was done using EDX, XRD, SEM, Raman, UV-Vis absorption spectrophotometer as well as photocurrent test of the CdS thin film under illumination using potentiostat with the three-electrode system. The EDX result indicated the presence of CdS with an elemental composition of Cd rich. XRD showed the appearance of CdS crystals in cubic and hexagonal formations. SEM image of CdS gave results in the form of crystals of less than 1 mm. Raman spectrum showed the appearance of CdS peaks. The bandgap of CdS was estimated to be 2.38 eV, and the photocurrent test confirmed that the film had a property of n-type semiconductor. Application of CdS thin film as a photoanode in the PFC system using 100 mg/L methylene blue solution showed degradation up to 48% for 2.5 h using a 4 cm2 photoanode, and the maximum potential of 0.8 V was obtained with a photoanode area of 1 cm2.
format article
author Gunawan Gunawan
Abdul Haris
Didik Setiyo Widodo
Linda Suyati
Wilman Septina
author_facet Gunawan Gunawan
Abdul Haris
Didik Setiyo Widodo
Linda Suyati
Wilman Septina
author_sort Gunawan Gunawan
title Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
title_short Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
title_full Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
title_fullStr Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
title_full_unstemmed Degradation of Methylene Blue Using Cadmium Sulfide Photoanode in Photofuel Cell System with Variation of Electrolytes
title_sort degradation of methylene blue using cadmium sulfide photoanode in photofuel cell system with variation of electrolytes
publisher Department of Chemistry, Universitas Gadjah Mada
publishDate 2020
url https://doaj.org/article/b9efcc85313745faaaff479481ae18f4
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