Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature

The effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The...

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Autores principales:	Naoshi Shimotomai, Hidetaka Nanao, Shigeyuki Mori
Formato:	article
Lenguaje:	EN
Publicado:	Japanese Society of Tribologists 2012
Materias:	nascent surface tribochemical reaction adsorption decomposition temperature Physics QC1-999 Engineering (General). Civil engineering (General) TA1-2040 Mechanical engineering and machinery TJ1-1570 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/b9f61627250546208094ed65755c5b22
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spelling	oai:doaj.org-article:b9f61627250546208094ed65755c5b222021-11-05T09:25:03ZTribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature1881-219810.2474/trol.7.54https://doaj.org/article/b9f61627250546208094ed65755c5b222012-04-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/7/2/7_2_54/_pdf/-char/enhttps://doaj.org/toc/1881-2198The effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The adsorption rate of benzene decreased with increasing temperature whereas desorption rate of hydrogen and adsorption rate of water increased. It appeared that water from residual gas preferentially adsorbed onto the nascent surface to disturb benzene adsorption as the temperature increased where the water was decomposed to form hydrogen. In this study, it was found that the reaction of adsorption on mechanically formed nascent surfaces is affected by temperature. Adsorption activity of mechanically formed nascent surfaces was calculated.Naoshi ShimotomaiHidetaka NanaoShigeyuki MoriJapanese Society of Tribologistsarticlenascent surfacetribochemical reactionadsorptiondecompositiontemperaturePhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 7, Iss 2, Pp 54-59 (2012)
institution	DOAJ
collection	DOAJ
language	EN
topic	nascent surface tribochemical reaction adsorption decomposition temperature Physics QC1-999 Engineering (General). Civil engineering (General) TA1-2040 Mechanical engineering and machinery TJ1-1570 Chemistry QD1-999
spellingShingle	nascent surface tribochemical reaction adsorption decomposition temperature Physics QC1-999 Engineering (General). Civil engineering (General) TA1-2040 Mechanical engineering and machinery TJ1-1570 Chemistry QD1-999 Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
description	The effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The adsorption rate of benzene decreased with increasing temperature whereas desorption rate of hydrogen and adsorption rate of water increased. It appeared that water from residual gas preferentially adsorbed onto the nascent surface to disturb benzene adsorption as the temperature increased where the water was decomposed to form hydrogen. In this study, it was found that the reaction of adsorption on mechanically formed nascent surfaces is affected by temperature. Adsorption activity of mechanically formed nascent surfaces was calculated.
format	article
author	Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori
author_facet	Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori
author_sort	Naoshi Shimotomai
title	Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
title_short	Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
title_full	Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
title_fullStr	Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
title_full_unstemmed	Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
title_sort	tribochemical reaction of benzene on nascent steel surface and effect of temperature
publisher	Japanese Society of Tribologists
publishDate	2012
url	https://doaj.org/article/b9f61627250546208094ed65755c5b22
work_keys_str_mv	AT naoshishimotomai tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature AT hidetakananao tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature AT shigeyukimori tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature
_version_	1718444370764496896

Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature

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