Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen

Gold catalysts have previously been reported for the epoxidation of alkenes with molecular oxygen. Here the authors show that, rather than the gold nanoparticles, the active species for this reaction are actually small, soluble gold species stabilized by the oxidised organic products.

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Autores principales:	Linping Qian, Zhen Wang, Evgeny V. Beletskiy, Jingyue Liu, Haroldo J. dos Santos, Tiehu Li, Maria do C. Rangel, Mayfair C. Kung, Harold H. Kung
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ba305534e6ab48a383a93d772020fb56
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spelling	oai:doaj.org-article:ba305534e6ab48a383a93d772020fb562021-12-02T15:38:33ZStable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen10.1038/ncomms148812041-1723https://doaj.org/article/ba305534e6ab48a383a93d772020fb562017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14881https://doaj.org/toc/2041-1723Gold catalysts have previously been reported for the epoxidation of alkenes with molecular oxygen. Here the authors show that, rather than the gold nanoparticles, the active species for this reaction are actually small, soluble gold species stabilized by the oxidised organic products.Linping QianZhen WangEvgeny V. BeletskiyJingyue LiuHaroldo J. dos SantosTiehu LiMaria do C. RangelMayfair C. KungHarold H. KungNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Linping Qian Zhen Wang Evgeny V. Beletskiy Jingyue Liu Haroldo J. dos Santos Tiehu Li Maria do C. Rangel Mayfair C. Kung Harold H. Kung Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
description	Gold catalysts have previously been reported for the epoxidation of alkenes with molecular oxygen. Here the authors show that, rather than the gold nanoparticles, the active species for this reaction are actually small, soluble gold species stabilized by the oxidised organic products.
format	article
author	Linping Qian Zhen Wang Evgeny V. Beletskiy Jingyue Liu Haroldo J. dos Santos Tiehu Li Maria do C. Rangel Mayfair C. Kung Harold H. Kung
author_facet	Linping Qian Zhen Wang Evgeny V. Beletskiy Jingyue Liu Haroldo J. dos Santos Tiehu Li Maria do C. Rangel Mayfair C. Kung Harold H. Kung
author_sort	Linping Qian
title	Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
title_short	Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
title_full	Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
title_fullStr	Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
title_full_unstemmed	Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
title_sort	stable and solubilized active au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/ba305534e6ab48a383a93d772020fb56
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Stable and solubilized active Au atom clusters for selective epoxidation of cis-cyclooctene with molecular oxygen

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