Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling

Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique...

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Autores principales: Xiao-Ye Wang, Marcus Richter, Yuanqin He, Jonas Björk, Alexander Riss, Raju Rajesh, Manuela Garnica, Felix Hennersdorf, Jan J. Weigand, Akimitsu Narita, Reinhard Berger, Xinliang Feng, Willi Auwärter, Johannes V. Barth, Carlos-Andres Palma, Klaus Müllen
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Publicado: Nature Portfolio 2017
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spelling oai:doaj.org-article:bae30ce09492472a96d838a85983c9542021-12-02T17:06:13ZExploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling10.1038/s41467-017-01934-12041-1723https://doaj.org/article/bae30ce09492472a96d838a85983c9542017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01934-1https://doaj.org/toc/2041-1723Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.Xiao-Ye WangMarcus RichterYuanqin HeJonas BjörkAlexander RissRaju RajeshManuela GarnicaFelix HennersdorfJan J. WeigandAkimitsu NaritaReinhard BergerXinliang FengWilli AuwärterJohannes V. BarthCarlos-Andres PalmaKlaus MüllenNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xiao-Ye Wang
Marcus Richter
Yuanqin He
Jonas Björk
Alexander Riss
Raju Rajesh
Manuela Garnica
Felix Hennersdorf
Jan J. Weigand
Akimitsu Narita
Reinhard Berger
Xinliang Feng
Willi Auwärter
Johannes V. Barth
Carlos-Andres Palma
Klaus Müllen
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
description Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.
format article
author Xiao-Ye Wang
Marcus Richter
Yuanqin He
Jonas Björk
Alexander Riss
Raju Rajesh
Manuela Garnica
Felix Hennersdorf
Jan J. Weigand
Akimitsu Narita
Reinhard Berger
Xinliang Feng
Willi Auwärter
Johannes V. Barth
Carlos-Andres Palma
Klaus Müllen
author_facet Xiao-Ye Wang
Marcus Richter
Yuanqin He
Jonas Björk
Alexander Riss
Raju Rajesh
Manuela Garnica
Felix Hennersdorf
Jan J. Weigand
Akimitsu Narita
Reinhard Berger
Xinliang Feng
Willi Auwärter
Johannes V. Barth
Carlos-Andres Palma
Klaus Müllen
author_sort Xiao-Ye Wang
title Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_short Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_full Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_fullStr Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_full_unstemmed Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_sort exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/bae30ce09492472a96d838a85983c954
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