Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling

Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique...

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Main Authors:	Xiao-Ye Wang, Marcus Richter, Yuanqin He, Jonas Björk, Alexander Riss, Raju Rajesh, Manuela Garnica, Felix Hennersdorf, Jan J. Weigand, Akimitsu Narita, Reinhard Berger, Xinliang Feng, Willi Auwärter, Johannes V. Barth, Carlos-Andres Palma, Klaus Müllen
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/bae30ce09492472a96d838a85983c954
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spelling	oai:doaj.org-article:bae30ce09492472a96d838a85983c9542021-12-02T17:06:13ZExploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling10.1038/s41467-017-01934-12041-1723https://doaj.org/article/bae30ce09492472a96d838a85983c9542017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01934-1https://doaj.org/toc/2041-1723Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.Xiao-Ye WangMarcus RichterYuanqin HeJonas BjörkAlexander RissRaju RajeshManuela GarnicaFelix HennersdorfJan J. WeigandAkimitsu NaritaReinhard BergerXinliang FengWilli AuwärterJohannes V. BarthCarlos-Andres PalmaKlaus MüllenNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
description	Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.
format	article
author	Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen
author_facet	Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen
author_sort	Xiao-Ye Wang
title	Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_short	Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_full	Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_fullStr	Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_full_unstemmed	Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
title_sort	exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/bae30ce09492472a96d838a85983c954
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Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling

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