Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique...
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Nature Portfolio
2017
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oai:doaj.org-article:bae30ce09492472a96d838a85983c9542021-12-02T17:06:13ZExploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling10.1038/s41467-017-01934-12041-1723https://doaj.org/article/bae30ce09492472a96d838a85983c9542017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01934-1https://doaj.org/toc/2041-1723Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.Xiao-Ye WangMarcus RichterYuanqin HeJonas BjörkAlexander RissRaju RajeshManuela GarnicaFelix HennersdorfJan J. WeigandAkimitsu NaritaReinhard BergerXinliang FengWilli AuwärterJohannes V. BarthCarlos-Andres PalmaKlaus MüllenNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
description |
Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character. |
format |
article |
author |
Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen |
author_facet |
Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen |
author_sort |
Xiao-Ye Wang |
title |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
title_short |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
title_full |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
title_fullStr |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
title_full_unstemmed |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
title_sort |
exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/bae30ce09492472a96d838a85983c954 |
work_keys_str_mv |
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