Observation of different reactivities of para and ortho-water towards trapped diazenylium ions

Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction.

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Autores principales: Ardita Kilaj, Hong Gao, Daniel Rösch, Uxia Rivero, Jochen Küpper, Stefan Willitsch
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/bb34a4a25a494bebb74605d27be6beb5
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spelling oai:doaj.org-article:bb34a4a25a494bebb74605d27be6beb52021-12-02T16:49:19ZObservation of different reactivities of para and ortho-water towards trapped diazenylium ions10.1038/s41467-018-04483-32041-1723https://doaj.org/article/bb34a4a25a494bebb74605d27be6beb52018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04483-3https://doaj.org/toc/2041-1723Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction.Ardita KilajHong GaoDaniel RöschUxia RiveroJochen KüpperStefan WillitschNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Ardita Kilaj
Hong Gao
Daniel Rösch
Uxia Rivero
Jochen Küpper
Stefan Willitsch
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
description Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction.
format article
author Ardita Kilaj
Hong Gao
Daniel Rösch
Uxia Rivero
Jochen Küpper
Stefan Willitsch
author_facet Ardita Kilaj
Hong Gao
Daniel Rösch
Uxia Rivero
Jochen Küpper
Stefan Willitsch
author_sort Ardita Kilaj
title Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
title_short Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
title_full Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
title_fullStr Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
title_full_unstemmed Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
title_sort observation of different reactivities of para and ortho-water towards trapped diazenylium ions
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/bb34a4a25a494bebb74605d27be6beb5
work_keys_str_mv AT arditakilaj observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
AT honggao observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
AT danielrosch observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
AT uxiarivero observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
AT jochenkupper observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
AT stefanwillitsch observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions
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