Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction.
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Nature Portfolio
2018
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oai:doaj.org-article:bb34a4a25a494bebb74605d27be6beb52021-12-02T16:49:19ZObservation of different reactivities of para and ortho-water towards trapped diazenylium ions10.1038/s41467-018-04483-32041-1723https://doaj.org/article/bb34a4a25a494bebb74605d27be6beb52018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04483-3https://doaj.org/toc/2041-1723Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction.Ardita KilajHong GaoDaniel RöschUxia RiveroJochen KüpperStefan WillitschNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018) |
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Science Q Ardita Kilaj Hong Gao Daniel Rösch Uxia Rivero Jochen Küpper Stefan Willitsch Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
description |
Water molecules exist as two distinct nuclear-spin isomers denoted ortho and para. Here, the authors separate these two isomers in the gas phase to show that they exhibit different reactivities in a prototypical proton-transfer reaction. |
format |
article |
author |
Ardita Kilaj Hong Gao Daniel Rösch Uxia Rivero Jochen Küpper Stefan Willitsch |
author_facet |
Ardita Kilaj Hong Gao Daniel Rösch Uxia Rivero Jochen Küpper Stefan Willitsch |
author_sort |
Ardita Kilaj |
title |
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
title_short |
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
title_full |
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
title_fullStr |
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
title_full_unstemmed |
Observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
title_sort |
observation of different reactivities of para and ortho-water towards trapped diazenylium ions |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/bb34a4a25a494bebb74605d27be6beb5 |
work_keys_str_mv |
AT arditakilaj observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions AT honggao observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions AT danielrosch observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions AT uxiarivero observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions AT jochenkupper observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions AT stefanwillitsch observationofdifferentreactivitiesofparaandorthowatertowardstrappeddiazenyliumions |
_version_ |
1718383358616010752 |