Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation

Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity...

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Autores principales:	Xiuquan Jia, Jiping Ma, Fei Xia, Mingxia Gao, Jin Gao, Jie Xu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bb5cd324d0c04ac7ad40dc8a20a29d89
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spelling	oai:doaj.org-article:bb5cd324d0c04ac7ad40dc8a20a29d892021-12-02T16:57:06ZSwitching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation10.1038/s41467-019-10315-92041-1723https://doaj.org/article/bb5cd324d0c04ac7ad40dc8a20a29d892019-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10315-9https://doaj.org/toc/2041-1723Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.Xiuquan JiaJiping MaFei XiaMingxia GaoJin GaoJie XuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
description	Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.
format	article
author	Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu
author_facet	Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu
author_sort	Xiuquan Jia
title	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_short	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_full	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_fullStr	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_full_unstemmed	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_sort	switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/bb5cd324d0c04ac7ad40dc8a20a29d89
work_keys_str_mv	AT xiuquanjia switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation AT jipingma switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation AT feixia switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation AT mingxiagao switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation AT jingao switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation AT jiexu switchingacidityonmanganeseoxidecatalystwithacetylacetonesforselectivitytunableaminesoxidation
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Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation

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