Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives, suggests that the pushing-from-below phenomenon may b...

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Autores principales:	Jingzhen Du, Carlos Alvarez-Lamsfus, Elizabeth P. Wildman, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bb7903e68b554b979a100c14040e7390
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spelling	oai:doaj.org-article:bb7903e68b554b979a100c14040e73902021-12-02T16:57:44ZThorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides10.1038/s41467-019-12206-52041-1723https://doaj.org/article/bb7903e68b554b979a100c14040e73902019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12206-5https://doaj.org/toc/2041-1723Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives, suggests that the pushing-from-below phenomenon may be more widespread than previously thought.Jingzhen DuCarlos Alvarez-LamsfusElizabeth P. WildmanAshley J. WoolesLaurent MaronStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-13 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jingzhen Du Carlos Alvarez-Lamsfus Elizabeth P. Wildman Ashley J. Wooles Laurent Maron Stephen T. Liddle Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
description	Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives, suggests that the pushing-from-below phenomenon may be more widespread than previously thought.
format	article
author	Jingzhen Du Carlos Alvarez-Lamsfus Elizabeth P. Wildman Ashley J. Wooles Laurent Maron Stephen T. Liddle
author_facet	Jingzhen Du Carlos Alvarez-Lamsfus Elizabeth P. Wildman Ashley J. Wooles Laurent Maron Stephen T. Liddle
author_sort	Jingzhen Du
title	Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
title_short	Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
title_full	Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
title_fullStr	Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
title_full_unstemmed	Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
title_sort	thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/bb7903e68b554b979a100c14040e7390
work_keys_str_mv	AT jingzhendu thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides AT carlosalvarezlamsfus thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides AT elizabethpwildman thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides AT ashleyjwooles thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides AT laurentmaron thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides AT stephentliddle thoriumnitrogenmultiplebondsprovideevidenceforpushingfrombelowforearlyactinides
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Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

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