Multi-modal mechanophores based on cinnamate dimers

Mechanochemistry offers exciting opportunities for molecular engineering of stress-responsive properties of polymers. Here the authors show that macrocyclic cinnamate dimers in a polymer chain can undergo dissociation on the sub-second timescale under 1–2 nN stretching to yield a chromophore that th...

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Autores principales:	Huan Zhang, Xun Li, Yangju Lin, Fei Gao, Zhen Tang, Peifeng Su, Wenke Zhang, Yuanze Xu, Wengui Weng, Roman Boulatov
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bbd24677f9464fa0a04eceeb58c2bca3
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spelling	oai:doaj.org-article:bbd24677f9464fa0a04eceeb58c2bca32021-12-02T15:39:00ZMulti-modal mechanophores based on cinnamate dimers10.1038/s41467-017-01412-82041-1723https://doaj.org/article/bbd24677f9464fa0a04eceeb58c2bca32017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01412-8https://doaj.org/toc/2041-1723Mechanochemistry offers exciting opportunities for molecular engineering of stress-responsive properties of polymers. Here the authors show that macrocyclic cinnamate dimers in a polymer chain can undergo dissociation on the sub-second timescale under 1–2 nN stretching to yield a chromophore that then can be optically healed.Huan ZhangXun LiYangju LinFei GaoZhen TangPeifeng SuWenke ZhangYuanze XuWengui WengRoman BoulatovNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Huan Zhang Xun Li Yangju Lin Fei Gao Zhen Tang Peifeng Su Wenke Zhang Yuanze Xu Wengui Weng Roman Boulatov Multi-modal mechanophores based on cinnamate dimers
description	Mechanochemistry offers exciting opportunities for molecular engineering of stress-responsive properties of polymers. Here the authors show that macrocyclic cinnamate dimers in a polymer chain can undergo dissociation on the sub-second timescale under 1–2 nN stretching to yield a chromophore that then can be optically healed.
format	article
author	Huan Zhang Xun Li Yangju Lin Fei Gao Zhen Tang Peifeng Su Wenke Zhang Yuanze Xu Wengui Weng Roman Boulatov
author_facet	Huan Zhang Xun Li Yangju Lin Fei Gao Zhen Tang Peifeng Su Wenke Zhang Yuanze Xu Wengui Weng Roman Boulatov
author_sort	Huan Zhang
title	Multi-modal mechanophores based on cinnamate dimers
title_short	Multi-modal mechanophores based on cinnamate dimers
title_full	Multi-modal mechanophores based on cinnamate dimers
title_fullStr	Multi-modal mechanophores based on cinnamate dimers
title_full_unstemmed	Multi-modal mechanophores based on cinnamate dimers
title_sort	multi-modal mechanophores based on cinnamate dimers
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/bbd24677f9464fa0a04eceeb58c2bca3
work_keys_str_mv	AT huanzhang multimodalmechanophoresbasedoncinnamatedimers AT xunli multimodalmechanophoresbasedoncinnamatedimers AT yangjulin multimodalmechanophoresbasedoncinnamatedimers AT feigao multimodalmechanophoresbasedoncinnamatedimers AT zhentang multimodalmechanophoresbasedoncinnamatedimers AT peifengsu multimodalmechanophoresbasedoncinnamatedimers AT wenkezhang multimodalmechanophoresbasedoncinnamatedimers AT yuanzexu multimodalmechanophoresbasedoncinnamatedimers AT wenguiweng multimodalmechanophoresbasedoncinnamatedimers AT romanboulatov multimodalmechanophoresbasedoncinnamatedimers
_version_	1718386011983052800

Multi-modal mechanophores based on cinnamate dimers

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