Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding

Product miniaturization is a constant trend in industries that demand ever-smaller products that can be mass produced while maintaining high precision dimensions in the final pieces. Ultrasonic micro injection molding (UMIM) technology has emerged as a polymer processing technique capable of achievi...

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Autores principales: Jackeline Iturbe-Ek, Alan O. Sustaita, Diego Aguilar-Viches, José Manuel Mata-Padilla, Carlos A. Ávila-Orta, Luis E. Elizalde, Alex Elías-Zúñiga, Luis Marcelo Lozano
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/bc1e719d85d641cfa7f3060c1b319683
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spelling oai:doaj.org-article:bc1e719d85d641cfa7f3060c1b3196832021-11-25T18:49:20ZInsights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding10.3390/polym132240102073-4360https://doaj.org/article/bc1e719d85d641cfa7f3060c1b3196832021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/4010https://doaj.org/toc/2073-4360Product miniaturization is a constant trend in industries that demand ever-smaller products that can be mass produced while maintaining high precision dimensions in the final pieces. Ultrasonic micro injection molding (UMIM) technology has emerged as a polymer processing technique capable of achieving the mass production of polymeric parts with micro-features, while still assuring replicability, repeatability, and high precision, contrary to the capabilities of conventional processing technologies of polymers. In this study, it is shown that the variation of parameters during the UMIM process, such as the amplitude of the ultrasound waves and the processing time, lead to significant modification on the molecular structure of the polymer. The variation of both the amplitude and processing time contribute to chain scission; however, the processing time is a more relevant factor for this effect as it is capable of achieving a greater chain scission in different areas of the same specimen. Further, the presence of polymorphism within the samples produced by UMIM is demonstrated. Similarly to conventional processes, the UMIM technique leads to some degree of chain orientation, despite the fact that it is carried out in a relatively small time and space. The results presented here aim to contribute to the optimization of the use of the UMIM process for the manufacture of polymeric micro parts.Jackeline Iturbe-EkAlan O. SustaitaDiego Aguilar-VichesJosé Manuel Mata-PadillaCarlos A. Ávila-OrtaLuis E. ElizaldeAlex Elías-ZúñigaLuis Marcelo LozanoMDPI AGarticleultrasonic injection moldingpolypropyleneproduct miniaturizationmolecular characterizationOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 4010, p 4010 (2021)
institution DOAJ
collection DOAJ
language EN
topic ultrasonic injection molding
polypropylene
product miniaturization
molecular characterization
Organic chemistry
QD241-441
spellingShingle ultrasonic injection molding
polypropylene
product miniaturization
molecular characterization
Organic chemistry
QD241-441
Jackeline Iturbe-Ek
Alan O. Sustaita
Diego Aguilar-Viches
José Manuel Mata-Padilla
Carlos A. Ávila-Orta
Luis E. Elizalde
Alex Elías-Zúñiga
Luis Marcelo Lozano
Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
description Product miniaturization is a constant trend in industries that demand ever-smaller products that can be mass produced while maintaining high precision dimensions in the final pieces. Ultrasonic micro injection molding (UMIM) technology has emerged as a polymer processing technique capable of achieving the mass production of polymeric parts with micro-features, while still assuring replicability, repeatability, and high precision, contrary to the capabilities of conventional processing technologies of polymers. In this study, it is shown that the variation of parameters during the UMIM process, such as the amplitude of the ultrasound waves and the processing time, lead to significant modification on the molecular structure of the polymer. The variation of both the amplitude and processing time contribute to chain scission; however, the processing time is a more relevant factor for this effect as it is capable of achieving a greater chain scission in different areas of the same specimen. Further, the presence of polymorphism within the samples produced by UMIM is demonstrated. Similarly to conventional processes, the UMIM technique leads to some degree of chain orientation, despite the fact that it is carried out in a relatively small time and space. The results presented here aim to contribute to the optimization of the use of the UMIM process for the manufacture of polymeric micro parts.
format article
author Jackeline Iturbe-Ek
Alan O. Sustaita
Diego Aguilar-Viches
José Manuel Mata-Padilla
Carlos A. Ávila-Orta
Luis E. Elizalde
Alex Elías-Zúñiga
Luis Marcelo Lozano
author_facet Jackeline Iturbe-Ek
Alan O. Sustaita
Diego Aguilar-Viches
José Manuel Mata-Padilla
Carlos A. Ávila-Orta
Luis E. Elizalde
Alex Elías-Zúñiga
Luis Marcelo Lozano
author_sort Jackeline Iturbe-Ek
title Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
title_short Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
title_full Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
title_fullStr Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
title_full_unstemmed Insights on the Molecular Behavior of Polypropylene in the Process of Ultrasonic Injection Molding
title_sort insights on the molecular behavior of polypropylene in the process of ultrasonic injection molding
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/bc1e719d85d641cfa7f3060c1b319683
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