Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensiv...
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Nature Portfolio
2019
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oai:doaj.org-article:bc4244d2082547389790ca708b0d09372021-12-02T16:57:06ZControlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation10.1038/s41467-019-12018-72041-1723https://doaj.org/article/bc4244d2082547389790ca708b0d09372019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12018-7https://doaj.org/toc/2041-1723Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensive starting material formic acid in the presence of D2O.Kohsuke MoriYuya FutamuraShinya MasudaHisayoshi KobayashiHiromi YamashitaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Kohsuke Mori Yuya Futamura Shinya Masuda Hisayoshi Kobayashi Hiromi Yamashita Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
description |
Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensive starting material formic acid in the presence of D2O. |
format |
article |
author |
Kohsuke Mori Yuya Futamura Shinya Masuda Hisayoshi Kobayashi Hiromi Yamashita |
author_facet |
Kohsuke Mori Yuya Futamura Shinya Masuda Hisayoshi Kobayashi Hiromi Yamashita |
author_sort |
Kohsuke Mori |
title |
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
title_short |
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
title_full |
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
title_fullStr |
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
title_full_unstemmed |
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
title_sort |
controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/bc4244d2082547389790ca708b0d0937 |
work_keys_str_mv |
AT kohsukemori controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation AT yuyafutamura controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation AT shinyamasuda controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation AT hisayoshikobayashi controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation AT hiromiyamashita controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation |
_version_ |
1718382644991885312 |