Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation

Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensiv...

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Autores principales: Kohsuke Mori, Yuya Futamura, Shinya Masuda, Hisayoshi Kobayashi, Hiromi Yamashita
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/bc4244d2082547389790ca708b0d0937
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spelling oai:doaj.org-article:bc4244d2082547389790ca708b0d09372021-12-02T16:57:06ZControlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation10.1038/s41467-019-12018-72041-1723https://doaj.org/article/bc4244d2082547389790ca708b0d09372019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12018-7https://doaj.org/toc/2041-1723Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensive starting material formic acid in the presence of D2O.Kohsuke MoriYuya FutamuraShinya MasudaHisayoshi KobayashiHiromi YamashitaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kohsuke Mori
Yuya Futamura
Shinya Masuda
Hisayoshi Kobayashi
Hiromi Yamashita
Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
description Hydrogen isotope compounds are useful in fine chemical production, but the natural abundance of these gases is low and the techniques used for producing D2 are expensive and energy intensive. Here, the authors develop a nanocatalyst that promotes selective production of D2 and HD from the inexpensive starting material formic acid in the presence of D2O.
format article
author Kohsuke Mori
Yuya Futamura
Shinya Masuda
Hisayoshi Kobayashi
Hiromi Yamashita
author_facet Kohsuke Mori
Yuya Futamura
Shinya Masuda
Hisayoshi Kobayashi
Hiromi Yamashita
author_sort Kohsuke Mori
title Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
title_short Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
title_full Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
title_fullStr Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
title_full_unstemmed Controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
title_sort controlled release of hydrogen isotope compounds and tunneling effect in the heterogeneously-catalyzed formic acid dehydrogenation
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/bc4244d2082547389790ca708b0d0937
work_keys_str_mv AT kohsukemori controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation
AT yuyafutamura controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation
AT shinyamasuda controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation
AT hisayoshikobayashi controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation
AT hiromiyamashita controlledreleaseofhydrogenisotopecompoundsandtunnelingeffectintheheterogeneouslycatalyzedformicaciddehydrogenation
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