Resonance and antiresonance in Raman scattering in GaSe and InSe crystals
Abstract The temperature effect on the Raman scattering efficiency is investigated in $$\varepsilon$$ ε -GaSe and $$\gamma$$ γ -InSe crystals. We found that varying the temperature over a broad range from 5 to 350 K permits to achieve both the resonant conditions and the antiresonance behaviour in R...
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2021
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oai:doaj.org-article:bc8dd62898a3458997fbe69b84ccd2132021-12-02T14:12:41ZResonance and antiresonance in Raman scattering in GaSe and InSe crystals10.1038/s41598-020-79411-x2045-2322https://doaj.org/article/bc8dd62898a3458997fbe69b84ccd2132021-01-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-79411-xhttps://doaj.org/toc/2045-2322Abstract The temperature effect on the Raman scattering efficiency is investigated in $$\varepsilon$$ ε -GaSe and $$\gamma$$ γ -InSe crystals. We found that varying the temperature over a broad range from 5 to 350 K permits to achieve both the resonant conditions and the antiresonance behaviour in Raman scattering of the studied materials. The resonant conditions of Raman scattering are observed at about 270 K under the 1.96 eV excitation for GaSe due to the energy proximity of the optical band gap. In the case of InSe, the resonant Raman spectra are apparent at about 50 and 270 K under correspondingly the 2.41 eV and 2.54 eV excitations as a result of the energy proximity of the so-called B transition. Interestingly, the observed resonances for both materials are followed by an antiresonance behaviour noticeable at higher temperatures than the detected resonances. The significant variations of phonon-modes intensities can be explained in terms of electron-phonon coupling and quantum interference of contributions from different points of the Brillouin zone.M. OsiekowiczD. StaszczukK. Olkowska-PuckoŁ. KipczakM. GrzeszczykM. ZinkiewiczK. NogajewskiZ. R. KudrynskyiZ. D. KovalyukA. PatanéA. BabińskiM. R. MolasNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-8 (2021) |
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Medicine R Science Q M. Osiekowicz D. Staszczuk K. Olkowska-Pucko Ł. Kipczak M. Grzeszczyk M. Zinkiewicz K. Nogajewski Z. R. Kudrynskyi Z. D. Kovalyuk A. Patané A. Babiński M. R. Molas Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
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Abstract The temperature effect on the Raman scattering efficiency is investigated in $$\varepsilon$$ ε -GaSe and $$\gamma$$ γ -InSe crystals. We found that varying the temperature over a broad range from 5 to 350 K permits to achieve both the resonant conditions and the antiresonance behaviour in Raman scattering of the studied materials. The resonant conditions of Raman scattering are observed at about 270 K under the 1.96 eV excitation for GaSe due to the energy proximity of the optical band gap. In the case of InSe, the resonant Raman spectra are apparent at about 50 and 270 K under correspondingly the 2.41 eV and 2.54 eV excitations as a result of the energy proximity of the so-called B transition. Interestingly, the observed resonances for both materials are followed by an antiresonance behaviour noticeable at higher temperatures than the detected resonances. The significant variations of phonon-modes intensities can be explained in terms of electron-phonon coupling and quantum interference of contributions from different points of the Brillouin zone. |
format |
article |
author |
M. Osiekowicz D. Staszczuk K. Olkowska-Pucko Ł. Kipczak M. Grzeszczyk M. Zinkiewicz K. Nogajewski Z. R. Kudrynskyi Z. D. Kovalyuk A. Patané A. Babiński M. R. Molas |
author_facet |
M. Osiekowicz D. Staszczuk K. Olkowska-Pucko Ł. Kipczak M. Grzeszczyk M. Zinkiewicz K. Nogajewski Z. R. Kudrynskyi Z. D. Kovalyuk A. Patané A. Babiński M. R. Molas |
author_sort |
M. Osiekowicz |
title |
Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
title_short |
Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
title_full |
Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
title_fullStr |
Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
title_full_unstemmed |
Resonance and antiresonance in Raman scattering in GaSe and InSe crystals |
title_sort |
resonance and antiresonance in raman scattering in gase and inse crystals |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/bc8dd62898a3458997fbe69b84ccd213 |
work_keys_str_mv |
AT mosiekowicz resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT dstaszczuk resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT kolkowskapucko resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT łkipczak resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT mgrzeszczyk resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT mzinkiewicz resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT knogajewski resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT zrkudrynskyi resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT zdkovalyuk resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT apatane resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT ababinski resonanceandantiresonanceinramanscatteringingaseandinsecrystals AT mrmolas resonanceandantiresonanceinramanscatteringingaseandinsecrystals |
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1718391807321047040 |