Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers

Tunnelling currents through molecular junctions are affected by quantum interference effects, but understanding the factors leading to them remains a challenge. Here the authors show that through-space conjugation in self-assembled monolayers leads to conformation-dependent quantum interference that...

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Autores principales:	Marco Carlotti, Andrii Kovalchuk, Tobias Wächter, Xinkai Qiu, Michael Zharnikov, Ryan C. Chiechi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bc973272ffd441a3bbf4d67a3c206266
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id	oai:doaj.org-article:bc973272ffd441a3bbf4d67a3c206266
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spelling	oai:doaj.org-article:bc973272ffd441a3bbf4d67a3c2062662021-12-02T15:35:46ZConformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers10.1038/ncomms139042041-1723https://doaj.org/article/bc973272ffd441a3bbf4d67a3c2062662016-12-01T00:00:00Zhttps://doi.org/10.1038/ncomms13904https://doaj.org/toc/2041-1723Tunnelling currents through molecular junctions are affected by quantum interference effects, but understanding the factors leading to them remains a challenge. Here the authors show that through-space conjugation in self-assembled monolayers leads to conformation-dependent quantum interference that suppresses conductivity.Marco CarlottiAndrii KovalchukTobias WächterXinkai QiuMichael ZharnikovRyan C. ChiechiNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Marco Carlotti Andrii Kovalchuk Tobias Wächter Xinkai Qiu Michael Zharnikov Ryan C. Chiechi Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
description	Tunnelling currents through molecular junctions are affected by quantum interference effects, but understanding the factors leading to them remains a challenge. Here the authors show that through-space conjugation in self-assembled monolayers leads to conformation-dependent quantum interference that suppresses conductivity.
format	article
author	Marco Carlotti Andrii Kovalchuk Tobias Wächter Xinkai Qiu Michael Zharnikov Ryan C. Chiechi
author_facet	Marco Carlotti Andrii Kovalchuk Tobias Wächter Xinkai Qiu Michael Zharnikov Ryan C. Chiechi
author_sort	Marco Carlotti
title	Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
title_short	Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
title_full	Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
title_fullStr	Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
title_full_unstemmed	Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
title_sort	conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/bc973272ffd441a3bbf4d67a3c206266
work_keys_str_mv	AT marcocarlotti conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers AT andriikovalchuk conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers AT tobiaswachter conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers AT xinkaiqiu conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers AT michaelzharnikov conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers AT ryancchiechi conformationdrivenquantuminterferenceeffectsmediatedbythroughspaceconjugationinselfassembledmonolayers
_version_	1718386498432139264

Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers

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